chemistry final

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combustion/synthesis (9)

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71 Terms

1

combustion/synthesis (9)

2 or more substances combine to form a single substance (A + B → AB)

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2

decomposition (9)

a single reactant is broken down into 2 or more products (AB → A + B)

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3

single replacement/single displacement (9)

a single element replaces a second element in a compound (A + Bx → B + Ax)

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4

double replacement/double displacement (9)

positive ions between 2 reacting compounds exchange places (Ax + By → Ay + Bx)

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5

combustion (9)

an element or a compound reacts with oxygen (X + O2 → ?)

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6

to predict products… (9)

identify the reaction type and use general formula

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7

to convert moles to particles (10)

moles x (6.022 x 10^23) = particles

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8

to convert grams to moles (10)

grams / molar mass = moles

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9

limiting reagent (11)

determines the amount of product that can be found

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10

excess reagent (11)

the reactant that is not completely used up

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11

theoretical yield (11)

100% of expected mass

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12

actual yield (11)

amount of mass actually formed

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13

5 points of kinetic theory (12)

  1. gas is made of particles

  2. all particles move in constant random motion

  3. all collisions are elastic

  4. higher temperature = more energy

  5. larger molecules move slower than smaller ones at the same temperature

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14

unit of temperature (12)

273 Kelvin (K) and 0 Celsius (C)

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15

SI unit for pressure (12)

atm

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16

STP (12)

101.3 kPa or 1 atm & 0 Celsius or 273 Kelvin

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17

absolute zero (12)

point where you have no energy

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18

how is kinetic energy related to temperature? (12)

at higher temperatures there is a wide range of energies, and at lower temperatures the range of kinetic energy is close to the same

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19

how is pressure affected by altitude? (12)

air exerts pressure because of gravity and decreases as you go up in elevation

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20

evaporation (12)

process of turning liquid to vapor (open vessel)

cooling process

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21

vaporization (12)

conversion of a liquid to a gas or vapor

warming process

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22

vapor pressure (12)

force exerted by a gas above a liquid

helps prevent evaporation and boiling

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23

boiling point (12)

the temperature at which a liquid boils

with altitude, boiling point lowers because it needs less kinetic energy

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24

melting point (12)

temperature that a solid turns into a liquid

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25

crystals (12)

solid, orderly, repeating structure

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26

crystal allotropes (12)

carbon = graphite is thin sheets

diamond = tetrahedral shape, rigid compact array

buchminster fullerine = 60 carbon hollow sphere

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27

amorphous solid (12)

solid that does not form crystals

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28

sublimation (12)

changing from a solid to a vapor without changing into a liquid

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29

variables that describe a gas (13)

pressure, volume, temperature, and number of moles

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30

Boyle’s law (13)

(pressure - volume relationship) at constant temperature the volume of a gas varies inversely with pressure

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31

Charles’s law (13)

(temperature - volume relationship) at constant pressure the volume of a gas is directly proportional with temperature

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32

Gay-Lussac’s law (13)

(temperature - pressure relationship) at constant volume pressure is directly proportional to Kelvin temperature of gas

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33

combined gas law (13)

using the three gas la ( ws we are able to see that there is a relationship between pressure, volume, and temperature

hold one of three variables constant

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34

ideal gas law (13)

has 3 of the variables that act on a gas

increase in moles = increase in pressure and volume

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35

Dalton’s law (13)

at constant volume and temperature total pressure exerted by a mixture is equal to the sum of the partial pressures of component gases

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36

Graham’s law of effusion (13)

the rate of effusion of a gas is inversely proportional to the square root of its molar mass

gases of lower molar mass effuse faster

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37

solution (14)

mixture of small particles

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38

solvent (14)

dissolving medium

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39

solute (14)

substance being dissolved

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40

suspension (14)

mixture where the particles will settle out if left undisturbed

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41

mixture (14)

2 or more substances physically combined

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42

colloid (14)

mixture of intermediate sized particles

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43

solubility (14)

amount of solute that can dissolve in a solvent (higher temp = more solubility)

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44

unsaturated (14)

more solute can dissolve in the substance but if more is added it disappears

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45

saturated (14)

no more solute can dissolve but if more is added will sink to the bottom

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46

supersaturated (14)

special situation where solvent holds more solute than it should and requires a series of steps to create

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47

Henry’s law (14)

solubility 1/pressure 1 = solubility 2/pressure 2

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48

electrolytes in solution (14)

(ionic compounds) number of particles is based on the number of separate ions a compound dissolves apart into

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49

nonelectrolytes in solution (14)

(covalent compounds) number of particles per compound and always equal to 1

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50

boiling point eleration (14)

boiling point of a solvent increases when a solute is dissolved in it

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51

freezing point depression (14)

freezing point of a solvent decreases when a solute is dissolved in it

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52

heat (15)

energy that flows from one object to another

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53

Hess’s law (15)

most reactions occur in a series of steps

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54

endothermic (15)

a reaction that absorbs energy and feels cold

equation: A + B + heat → C + D or A + B → C + D AH = +

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55

exothermic (15)

a reaction that releases energy and feels warm

equation: A + B → C + D + heat or A + B → C + D AH = -

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56

heat capacity (15)

the amount of heat required to change the temperature of a given amount of matter by 1 degree

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57

specific heat (15)

the amount of energy required to raise 1 gram of a substance by 1 degree C

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58

spontaneous reactions (15)

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59

free energy (15)

maximum amount of energy that can be used to do useful work

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60

relationship between directly proportional and inversely proportional (13)

inversely proportional has one that goes up and goes down and directly proportional has either both go up or both go down

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61

how to differentiate between colloid and suspension (14)

suspension has multiple phases and colloids have one

colloid uses the tyndall effect and suspension does not

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62

what is conserved in a reaction (11)

mass and particles

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63

spontaneous process (15)

any chemical of physical change that, once begun, occurs with not outside intervention

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64

2 things that determine spontaneous processes (15)

entropy - measure of disorder in a system

enthalpy - the heat of a system when it is under constant pressure

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65

convert moles to volume (10)

1 mol = 22.4 L

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66

5 things that affect the rate of solution (14)

agitation, temperature, surface area, pressure, and saturation

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67

reaction (15)

deltaH rxn

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68

formation (15)

deltaH f degrees = 0

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69

fusion (15)

heat required to melt 1 mol of a substance

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70

solution (15)

deltaH when dissolved

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71

combustion (15)

deltaH of reaction where combustion occurs

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