m3: alcohols/phenols/ethers

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14 Terms

1
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what is produced from a dehydration of an alcohol at a higher temperature?

an alkene and H2O

2
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what is produced from the dehydration of an alcohol at a lower temperature?

an ether

3
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what is produced from the oxidation of a primary alcohol?

an aldehyde and water

4
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what is produced from the oxidation of an aldehyde?

carboxylic acid

5
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what is produced from the oxidation of a secondary alcohol?

a ketone and H2O

6
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can a ketone be oxidized?

no

7
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can tertiary alcohols be oxidized?

no, because there is no hydrogen on the carbon to which the hydroxyl group is attached

8
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why are phenols able to act as weak acids?

the negative charge of the oxygen (after donating a proton) is stabilized by resonance that can occur with the aromatic group

9
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do phenols form stronger or weaker hydrogen bonds?

stronger, because the dipole is stabilized by resonance with the aromatic group

10
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do phenols have higher or lower melting and boiling points?

higher, due to the fact that they can form stronger hydrogen bonds

11
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what is the structure of an ether?

R-O-R

12
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can ethers form hydrogen bonds?

they can with H2O, but not in pure state

13
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do ethers have a higher or lower boiling point than alcohols?

lower, because they cannot form hydrogen bonds in the pure state, and are less polar

14
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do ethers react easily?

no, but they are very flammable (can undergo combustion reactions)