SL Chem - Unit #1: Electronegativity

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15 Terms

1

Electronegativity

The ability for an atom to attract and hold onto electrons

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2

Electronegativity trend on the periodic table

On the periodic table it electronegativity increases by going up diagonally towards the top right (Uses the Pauling Scale)

<p>On the periodic table it electronegativity increases by going up diagonally towards the top right (Uses the Pauling Scale)</p>
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3

Electronegativity trends going down the group

It decreases down a group

  • This is because of a greater shielding affect and lower affective nuclear charge making the valence electrons more loosely held and easier to rid of (rather than attracting electrons)

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4

Electronegativity trends going across the period (to the right)

It increases as we go across the row

  • Because more protons in the nucleus creates a stronger effective nuclear charge that attracts and holds onto electrons a lot better

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5

Electronegativity for Noble Gases

Noble gasses are stable elements (already have a full valence shell) that don’t attract any electrons so they have no electronegativity value

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6

Diatomic

Elements that can self stabilize by creating covalent bonds with themselves to create a stable shell

  • HOFBrINCl

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7

Monoatomic

An element that is naturally found on it’s own because it’s already stable and doesn’t need to bond with anything else to stabilize

  • All Noble Gases

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8

Pauling Scale

Is the scale that measures the strength of bonds between covalent bonds

  • Despite being derived from physical quantities (the bonds energy) the electronegativity number itself have no value, they are just used for comparative ways among themselves

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9

Electrostatic Charge

The interaction that between a covalent bond that helps hold them together

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10

Electronegativity Difference In Ionic Bonds

ΔEn ≥ 1.7

  • The electron is fully transferred between atoms making the dipole moment either ±

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11

Electronegativity Difference In Polar Covalent Bonds

0.5 ≤ ΔEn < 1.7

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12

Electronegativity Difference In Non-Polar Covalent Bonds

0 < ΔEn < 0.5

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13

Non-Polar Covalent

The electron is equally shared between both elements and it’s located in the middles

  • No dipole Moment

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14

Polar Covalent

The electron is shared unbalanced between the two, the atom with the higher electronegativity pulls the electron towards itself more than the other

  • It has partial dipole movement

    • Slight negative end: “δ− “

    • Slightly positive end: “δ+”

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15

Which End is δ− / δ+

the element that has a higher electronegativity is the δ- end of the bond

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