electron configuration

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page 3-5 25/7/25 note;

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10 Terms

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electron configuration is

electron arrangement in orbitals

2
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energy level diagram

  • visual representation of levels

  • s: one orbital

  • p: three orbitals, px, py, pz

  • d: five orbitals

  • f: ten orbitals

  • s starts at 1

  • p starts at 2

  • d starts at 3

  • f starts at 4

<ul><li><p>visual representation of levels</p></li><li><p>s: one orbital</p></li><li><p>p: three orbitals, p<sub>x</sub>, p<sub>y</sub>, p<sub>z</sub></p></li><li><p>d: five orbitals</p></li><li><p>f: ten orbitals</p></li><li><p>s starts at 1</p></li><li><p>p starts at 2</p></li><li><p>d starts at 3</p></li><li><p>f starts at 4</p></li></ul><p></p>
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aufbau’s principle

fill lower energy orbitals with electrons first before moving up to higher energy orbitals

<p>fill lower energy orbitals with electrons first before moving up to higher energy orbitals </p>
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Hund’s rule

every orbital must be occupied by one electron first, before the electrons are paired up

<p>every orbital must be occupied by one electron first, before the electrons are paired up </p>
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Pauli’s exclusion principle

no electron can have the same four quantum numbers, atleast one WILL differ, double check work if not

<p>no electron can have the same four quantum numbers, atleast one WILL differ, double check work if not </p>
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quantum number of families on periodic table

  • top to bottom

  • alkali and alkaline earth metals, including helium: 1s, 2s, 3s, 4s, 5s, 6s, 7s

  • transition metals: 3d, 4d, 5d, 6d

  • nonmetals: 2p, 3p, 4p, 5p, 6p

  • lanthanides: 4f, 5f

<ul><li><p>top to bottom</p></li><li><p>alkali and alkaline earth metals, including helium: 1s, 2s, 3s, 4s, 5s, 6s, 7s</p></li><li><p>transition metals: 3d, 4d, 5d, 6d</p></li><li><p>nonmetals: 2p, 3p, 4p, 5p, 6p</p></li><li><p>lanthanides: 4f, 5f</p></li></ul><p></p>
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complete electron configuration

  • will go in order of Aufbau’s principle and end at quantum number of associated spot on periodic table

  • exponent indicates position on period (row)

  • total sum of exponents indicates number of electrons and

<ul><li><p>will go in order of Aufbau’s principle and end at quantum number of associated spot on periodic table </p></li><li><p>exponent indicates position on period (row)</p></li><li><p>total sum of exponents indicates number of electrons and </p></li></ul><p></p>
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condensed electron configuration

start with noble gas before element and add rest of orbitals

<p>start with noble gas before element and add rest of orbitals </p>
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special stability

  • when electron is promoted to next orbital

  • mainly with d orbitals

  • only with exponent 4 or 9

  • d orbital has one electron in four orbitals and a full s orbital → one electron from s moves to empty d

  • d orbital has four full orbitals, one half full, and a full s orbital → one electron from s moves to last d orbital

<ul><li><p>when electron is promoted to next orbital</p></li><li><p>mainly with d orbitals</p></li><li><p>only with exponent 4 or 9</p></li><li><p>d orbital has one electron in four orbitals and a full s orbital → one electron from s moves to empty d </p></li><li><p>d orbital has four full orbitals, one half full, and a full s orbital → one electron from s moves to last d orbital</p></li></ul><p></p>
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electron configuration for ions

  • electrons do not equal protons

  • add lost or gained electrons to toal

  • adjust in exponents

  • may be equal to another element

<ul><li><p>electrons do not equal protons</p></li><li><p>add lost or gained electrons to toal</p></li><li><p>adjust in exponents </p></li><li><p>may be equal to another element </p></li></ul><p></p>