Oxidation in alcohols

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What are the 3 types of alcohols?

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<p>1 degree = OH group is attached to 1 alkyl</p><p>2 degrees = OH group is attached to a carbon atom that is bonded to 2 alkyl groups </p><p>3 degrees = OH group is attached to a carbon atom that is bonded to 3 alkyl groups</p>

1 degree = OH group is attached to 1 alkyl

2 degrees = OH group is attached to a carbon atom that is bonded to 2 alkyl groups

3 degrees = OH group is attached to a carbon atom that is bonded to 3 alkyl groups

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What can each type of alcohol oxidise into?

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2 degree = ketone

1 degree = aldehyde

1 degree = carboxylic acid

aldehyde = carboxylic acid

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12 Terms

1
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What are the 3 types of alcohols?

1 degree = OH group is attached to 1 alkyl

2 degrees = OH group is attached to a carbon atom that is bonded to 2 alkyl groups

3 degrees = OH group is attached to a carbon atom that is bonded to 3 alkyl groups

<p>1 degree = OH group is attached to 1 alkyl</p><p>2 degrees = OH group is attached to a carbon atom that is bonded to 2 alkyl groups </p><p>3 degrees = OH group is attached to a carbon atom that is bonded to 3 alkyl groups</p>
2
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What can each type of alcohol oxidise into?

2 degree = ketone

1 degree = aldehyde

1 degree = carboxylic acid

aldehyde = carboxylic acid

3
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What is important when showing the oxidation?

The functional groups must be in the same spot in the reactants and products

4
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What is the oxidising agent?

Acidified potassium dichromate

5
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When is distillation and reflux used?

1 degree to aldehyde, you use distillation

1 degree to carboxylic acid, you use reflux

2 degree to ketone, you use reflux

6
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When is water not produced in oxidation?

From aldehyde to carboxylic acid

7
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What is elimination in dehydration of alcohols?

The removal of a small molecule

8
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What does a dehydration of alcohol equation look like?

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<p>.</p>
9
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What could the 3 different outcomes of the dehydration be?

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10
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What happens during a substitution reaction and what is needed?

Alcohol turns into a haloalkane, a sodium halide and sulfuric acid is need.

11
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What reacts first in the substitution?

The sodium halide and sulfuric acid, creating a hydrogen halide.

12
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What does the substitution react look like?

.

<p>.</p>