Topic 6a : Rates of Reaction

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What is a rate of a chemical reaction ?

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1

What is a rate of a chemical reaction ?

how fast the reactants are changed into products

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2

Name 3 examples of reactions going from pretty slow to really fast ?

  1. the rusting of iron (pretty slow)

  2. A metal (e.g. magnesium) reacting with an acid to produce a gentle stream of bubbles (moderate speed)

  3. An explosion (really fast)

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3

what 4 main conditions affect the rate of reaction ?

  1. Temperature — the higher the temperature, the faster the reaction

  2. Concentration (or pressure for gases) - the more concentrated the reactants (or the higher the pressure), the faster the reaction

  3. Surface area (depends on the size of solid pieces) — the larger the surface area (the smaller the pieces), the faster the reaction

  4. Catalysts — the more catalysts present , the faster the reaction

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4

As stated in Collision Theory what 2 factors affect the rate of reaction ?

  1. The collision frequency of reacting particles (how often they collide).The more there are in a certain amount of time, the faster the reaction is.

    • as collision frequency increases , the probability for successful collisions increases

  2. The energy transferred during a collision. Particles have to collide with enough energy to be successful.

    • as the energy of collisions increase , the more collisions are successful

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5

what is activation energy ?

the minimum amount of energy that particles must have in order to react

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6

Which of the prementioned conditions affect the frequency of collisions ? (3)

  1. (Increase in) Temperature -

    • temperature increases

    • particles move quicker

    • particles collide more often

    • more frequent collision means faster rate of reaction

  2. (Increase in) Concentration/Pressure (for gasses) -

    • solution is made more concentrated

    • there are more particles of reactants colliding between the water molecules

    • collisions of the particles of reactants are more likely

    • more frequent collisions means faster rate of reaction

  3. (Increase in) Surface area to volume ration -

    • the surface area : volume of a solid increases when your break into smaller bodies

    • for the same volume of solid , the particles surrounding

    • it in the solution have a larger surface area to work on

    • more frequent collisions means faster rate of reaction

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7

Which of the prementioned conditions affect the energy of collisions ? (1)

  1. (Increase in) Temperature -

    • increase in temperature

    • increase in speed of particles as they collide (increase in energy of collision)

    • there are more particles colliding with enough energy to react successfully

  2. Catalysts

    • they decrease the activation energy needed for the reaction to occur by providing an alternative reaction pathway with a lower activation energy

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8

what is a Catalyst ?

A catalyst is a substance which can speed up a reaction without being changed or used up in the reaction

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9

what is an Enzyme ?

A biological catalyst that works similarly to all other catalysts but will generally only catalyse a certain reaction for a specific molecule

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