Kinetics Recall

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12 Terms

1
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Transition state

Molecular structure as they cross energy barrier - at energy maxima

2
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Intermediate

Forms between different states - at energy minima

3
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Integrated form of 0th order rate law

[A]=[A]o-kt

4
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Integrated form of 1st order rate law

ln[A]=ln[A]o-kt

5
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Integrated form of 2nd order rate law

1/[A]= 1/[A]o +kt

6
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Show how to derive integrated 1st order rate law

7
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Show how to derive integrated 2nd order rate law

8
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Arrhenius equation(shows how rate depends on temperature

k=Ae(-Ea/RT)

9
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Michalis menten enzyme kinetic lineweaver Burke plot

1/V= 1/Vmax+(Km/vmax)1/[S]

10
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Zero order half life

t1/2 = [Ao]/2k

11
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1st order half life

t1/2 =ln2/k

12
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2nd order half life

t1/2=k/[Ao]