239 Amines Reactions

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9 Terms

1
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CN —> NH2

  1. LAH

  2. H2O

2
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COOH —> ONH2 —> NH2

  1. SOCl2

  2. NH3

  1. LAH

  2. H2O

3
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NO2 —> NH2

H2, Pt

or

  1. Zn, H+ (H3O+, HCl)

  2. NaOH

4
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Gabriel Synthesis

* only makes primary amines

<p>* only makes primary amines</p><p></p>
5
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Reductive Amination

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6
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Hoffman Elimination

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7
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Diazonium Salt Formation

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8
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Diazonium Salt Reaction

Reagent, X

  • H2O → OH

  • HBF4 → F

  • HCl, CuCl → Cl

  • HBr, CuBr → Br

  • KCN, CuCN → CN

  • KI → I

  • H3PO2 → H

<p>Reagent, X </p><ul><li><p>H2O → OH</p></li><li><p>HBF4 → F</p></li><li><p>HCl, CuCl → Cl</p></li><li><p>HBr, CuBr → Br</p></li><li><p>KCN, CuCN → CN</p></li><li><p>KI → I</p></li><li><p>H3PO2 → H</p></li></ul><p></p>
9
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Azo Coupling

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