Isomers

Level 3 Organic Chemistry

constitutional isomers have the same ______ and ____ of atom, but different atom-to-atom _____ or “structural _______”

number, type, connections, formula

repositioning of a functional group with an organic molecule is example of ______ isomerism

consitutional

______ include geometric and optical isomers

stereoisomers

________ isomers have the same atom-to-atom connections, and number and type of atoms; however, they have different ___ geometry

geometric, 3D

geometric isomers have ______ and ______ forms

cis, trans

______ means same; ______ means different

cis, trans

geometric isomers require a ______ ______ bond which ______ ______

double C=C, restricts rotation

geometric isomers require _ different ______ on each C atom in the C=C bond

2, groups

______ isomers require a chiral carbon

optical

a ______ carbon has __ different groups/environments attached

chiral, 4

enantiomers will ______ plane polarised ______ in different ______ to make pair of ____-________ ______ images called _________

rotate, light, directioins, non-superimposable mirror, enantiomers

enantiomers have the same ______ properties (melting and boiling points, solubility, polarity) since they share the same ______ groups, s_____ and m______ m____

physical, functional, shape, molar mass

enantiomers have the same ______ properties with ______ ______ chemicals, since they have the same ______ groups and reactions are not ________

chemical, optically inactive, functional, stereospecific

enantiomers have _______ chemical properties with ______ ______ chemicals (biochemical, smell, enzymes) since reactions are ________

different, optically active, stereospecific