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cation exchange capacity (CEC)
sum of total cations that a given soil can absorb
higher CEC soils
clayey soils and soils with humus (organic matter)
cation exchange influences
strength of adsorption, relative concentration of cations in the soil solution
ismorphic substitution
process in which one element substitutes another of comparable size in the crystalline structure. permeant charge
pH dependent charge
broken ends of clays carry a charge. Charge can change based on the pH. Lower pH = more H+ will attach to the broken ends.
acid soil pH
below 7.0
metals toxic to plants at low pH
Fe, Mn, Cu, Zn
P binds at low pH to
Fe/Al
P binds at high pH to
Ca
buffering capacity
soils ability to resist change in pH
active acidity
H+ or Al3+ in the water of soil and a measure of how acidic the soil is.
Exchangeable acidity
H+ and Al3+ that are on exchange sites of clay or OM negative sites
Residual acidity
H+ or Al3+ that are bound to clay or OM and NOT exchangeable
benefits of liming
crop yield improvement, nutrient availability, improved microbial activity, improved legume fixation of N
Calcium Carbonate Equivalent (CCE)
Neutralizing value of any liming material compared to pure calcium carbonate
factors to increase lime
higher: CCE, buffering capacity, CEC, pure lime, smaller lime particle, clay
soil colloid
fine, chemically active particles in soil
phyllosilicate
clay minerals constructed from tetrahedral and octahedral sheets
2:1 phyllosilicate clays
two tetrahedral sheet to one octahedral sheet. (illite, younger soils (mollisols, alfisols), shrink swell soils (vertisols))
1:1 phyllosilicate clays
one tetrahderal sheet to one octahedral sheet. (kaolinite, older/more weathered soils (spodosols, utisols))
iron and aluminum oxides
just octahedral sheets. common in highly weathered soils (oxisols)
humus
organic matter fraction that has decomposed sufficiently so that the source material is no longer recognizableprop
properties of humus
darker color soil, very chemically reactive, buffers soil pH, high CEC
nitrate lost easily by
leaching
ammonium lost easily by
volatilization
symbiotic biological N fixation
bacteria fix N2 to plant-available forms for plants to use
mineralization
biological conversation of unavailable organic N into plant available inorganic N (organic N to ammonium to nitrate)
immobilization
biological conversation of plant available N into unavailable organic N
ammonification
conversion of organic N to ammonium by microorganismswh
ammonification properties
needs warm temps, good soil moisture, oxygen supply. makes soil more basic (higher pH)
nitrification
conversion of ammonium to nitrite and then nitrate
nitrification properties
needs warm temps and well-drained soil. makes soil more acidic (lower pH)
nitrosomonas
mediates ammonium to nitrite
nitrobacter
mediates nitrite to nitrate
volatilization
removal of N from the soil by turning it into a gas that leaves the soil
denitrification
conversion of nitrate to a gas from of N (N2)
denitrification properties
needs warm temps, low oxygen, high organic matter
crop uptake and removal
removal of N by plants and then removing plant residues from the field
law of the minimum
if one growth factor/nutrient is deficient, plant growth is limited, even if all other factors/nutrients are adequate. plant growth is improved by increasing the supply of the deficient factor/nutrient
structural components
carbon, hydrogen, oxygen
primary macronutrient
nitrogen, phosphorus, potassium
secondary macronutrient
calcium, magnesium, sulfur
mass flow
dissolved nutrients move to the root in soil water that is flowing towards
diffusion
nutrients move from higher concentration in the bulk soil solution to lower concentration at the root
root interception
roots obtain nutrients by physically contacting nutrients in soil solution or on soil surfaces
a bag of 10-10-10 fertilizer
10% plant available N, 10% P2O5, 10% K2O
a bag of 16-0-8 fertilizer
16% plant available N, 0% P2O5, 8% K2O
phosphorus binds to
Fe and Al oxides (so it stays where it is placed in the soil)
how is P most likely to be lost
erosion (moves little within the profile)
what soil texture has lowest buffering capacity
sand
what soil texture needs most amount of lime to change from pH 4 to 5
clay
what plant element is needed in the largest quantity
carbon