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Synthesis of ether - primary alcohols with acid
R-OH + H30+
Synthesis of ether - Williamson ether synthesis
R-OH —> R-O-R
1. NaH, THF
2. R-X
Synthesis of ether - Silver oxide ether formation
R-OH + R-X/AgO2 —> R-O-R
Synthesis of ether - Alkoxymercuration of alkenes
R=R —> R-R-O-R
(CF3CO2)2Hg, R-OH
NaBH4
Reaction of ethers - acidic cleavage (also applicable for epoxide opening)
HX
Reaction of ethers - Claisen rearrangement
NaH, THF
XR=R
Preparation of epoxide - alkene with peroxyacid
mCPBA
Or
RCO3H
Reaction of ethers - Based catalyzed epoxide opening
-OH and H2O
Reaction of ethers - Grignard reagent
MgXR, ether solv./H3O+
Synthesis of thiols (from alkyl halides RCH2X)
(H2N)2X=S
H2O, NaOH
Oxidation of thiols
X2/Zn, H+
or
X2, H2O
Synthesis of sulfides
RX
THF
Oxidation of sulfides
H2O2
mCPBA or RCO3H