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proton transfer
a proton is transferred from an acid to a base
biomolecular nucelophilic subsitution
Sn2
substrate undergoes subsitution
coordination
bond formation
heterolysis
bond is broken and the two electrons end up on one of the atoms initially involved in the bond
nucleophilic addition
nucleophile is added using breaking of pi bond
nucleophile elimination
nucleophile leaving creates pi bond
biomolecular elimination
E2
strong base attacks a substrate in which a leaving group and a hydrogen atom are on adjacent carbons
electrophilic addition
nonpolar pi bond donates electrons to strongly electron deficient species (E+) forming a bond
electrophile elimination
electrophile eliminated from carbocation, generating a stable, uncharged, organic species
carbocation rearrangement
1,2 hydride shift
1,2 alkyl shift
Migration of an atom or group to an adjacent atom