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Colligative Properties
A property that depends only on the number of solute particles
Four Colligative Properties
Vapor Pressure Depression
Freezing Point Depression
Boiling Point Depression
Osmosis
Freezing Point Depression
When substance freezes, particles arrange into orderly arrangement to form solid
Freezing Point lowers when solute is added, the solvent particles are attracted to the solute and the solid arrangement becomes disarray
Molal Freezing Point constant
Kf H20= 1.86 C/m
Change in Freezing Point Formula
Tf = iKfm
Electrolytes
Substances that conduct electric currents as the result of a dissociation into positive and negative ions
Nonelectrolytes
molecular compounds (non conductors)
Which Solution has lower Freezing Point: 3 mol N2O5 or 2 mol Ca(NO3)2
Ca(NO3)2 because it has more particles
Vapor Pressure
The pressure of vapor above a liquid
Decreases when solute particles added because solvent attracted to solute. The solute leaves as a vapor
Which has higher vapor pressure: 1 mol NH4NO3 or 1 mol AlBr3
1 mol NH4NO3 because it has weaker bond.
Boiling Point Elevation
Boiling point increases when a solute is added because the solvent particles are attracted to the solute, so they do not leave and become gas.
Change in Boiling Point Formula
Tb= iKbm
Kb = 0.512 C/m
Osmosis- Osmotic Pressure
Osmosis is the net movement of solvent toward the solution with higher solute cone
Semipermeable
Materials that only allow some molecules to pass through
Molarity
Ratio of the moles of solute over liter of solution
Molality
Ratio of moles of solute over kilograms of solvent