Chem exam 3

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20 Terms

1

resonance

situation in which one Lewis structure is

insufficient to describe the bonding in a

molecule and the average of multiple

structures is observed

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2

ideal gas

hypothetical gas whose physical properties

are perfectly described by the gas laws

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3

valence bond theory

model that describes the changes in the atomic

orbitals of an atom when it forms a covalent

compound

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4

Dalton’s law of partial

pressures

total pressure of a mixture of ideal gases is

equal to the sum of the partial pressures of the

component gases

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5

pi bond (π pi)

bond formed by side-by-side overlap of

atomic orbitals, in which the electron density

is found on opposite sides of the internuclear

axis

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6

diffusion

movement of an atom or molecule from a

region of relatively high concentration to one

of relatively low concentration

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7

hybridization

description of bonding that involves atomic

orbitals overlapping to form σ or π bonds,

within which pairs of electrons are shared

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8

valence shell electron-pair

repulsion theory (VSEPR

theory used to predict the bond angles in a

molecule based on positioning regions of high

electron density as far apart as possible to

minimize electrostatic repulsion

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9

hypervalent molecule

molecule containing at least one main group

element that has more than eight electrons in

its valence shell

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10

covalent bond

bond formed when electrons are shared

between atoms

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11

Lewis symbol

symbol for an element or monatomic ion that

uses a dot to represent each valence electron

in the element or ion

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12

hybrid orbital

orbital created by combining atomic orbitals

on a central atom

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13

formal charge

charge that would result on an atom by taking

the number of valence electrons on the neutral

atom and subtracting the nonbonding

electrons and the number of bonds

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14

ideal gas law

relation between the pressure, volume,

amount, and temperature of a gas under

conditions derived by combination of the

simple gas laws

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15

effusion

transfer of gaseous atoms or molecules from a

container to a vacuum through very small

openings

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16

ionization energy

energy required to remove an electron from a

gaseous atom or ion

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17

sigma bond (σ bond)

covalent bond formed by overlap of atomic

orbitals along the internuclear axis

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18

electron-pair geometry

arrangement around a central atom of all

regions of electron density (bonds, lone pairs,

or unpaired electrons)

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19

electromagnetic radiation

energy transmitted by waves that have an

electric-field component and a magnetic-field

component

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20

ionic bond

strong electrostatic force of attraction between

cations and anions in an ionic compound

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