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Vocabulary flashcards covering properties of gases, kinetic theory, molar volume, density, diffusion, Graham’s law, partial pressures, Dalton’s law, atmospheric and clinical pressure measurement devices, barometric units (Torr/mmHg), hyperbaric pressure, Henry’s law, and solubility concepts.
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Gas
A substance that exerts pressure, can flow, and fill available space; gases are readily compressed/expanded and diffuse.
Pressure
Force per unit area exerted by a gas on its surroundings.
Viscosity
Internal friction to flow; a property exhibited by gases (and liquids) affecting flow.
Diffusion
Spread of molecules from regions of higher concentration to lower concentration; in gases, diffusion occurs rapidly.
Kinetic energy
The internal energy of a gas largely due to molecular motion; increases with temperature.
Avogadro’s Law
Equal volumes of gases at the same temperature and pressure contain the same number of molecules; one mole represents the amount of substance.
Molar volume
Volume occupied by one mole of a gas; under the same conditions, all gases have the same molar volume.
STPD
Standard Temperature and Pressure Dry: 0°C and 760 mmHg (dry gas).
22.4 L
Ideal molar volume of a gas at STPD: one mole occupies 22.4 liters.
Density
Mass per unit volume; high density indicates heavy particles, low density indicates light particles.
Gaseous diffusion
Movement of gas molecules from high to low concentration, spreading out until uniform.
Graham’s Law
Rate of diffusion of a gas is inversely proportional to the square root of its gram molecular weight.
Gram molecular weight (GMW)
Molar mass of a gas expressed in grams per mole.
Partial pressure
Pressure contributed by a single component of a gas mixture.
Dalton’s Law
Total pressure of a gas mixture equals the sum of its component partial pressures; each partial pressure is proportional to its fractional concentration.
Ptotal
Total pressure of a gas mixture.
Fractional concentration
The decimal fraction representing a gas’s percentage in a mixture.
Hyperbaric pressure
Pressure greater than atmospheric pressure.
Barometer
Device used to measure atmospheric pressure.
Mercury barometer
Barometer that uses a column of mercury to measure pressure.
Torr
Unit of pressure; 1 Torr equals 1 mmHg at sea level.
mmHg
Millimeters of mercury; unit of pressure used in barometry.
Aneroid barometer
Mechanical pressure gauge without liquid (uses springs) to measure pressure.
Manometer
Device to measure pressure using a liquid column; used at bedside for blood or airway pressures.
Pressure transducer
Device that converts pressure into an electrical signal (e.g., strain-gauge transducer).
Henry’s Law
The amount of gas dissolved in a liquid is proportional to its partial pressure above the liquid.
Solubility
The ability of a gas to dissolve in a liquid.
Solubility coefficient
The volume of gas that will dissolve in 1 mL of liquid at standard conditions; temperature affects solubility.
Dissolved gas volume
Volume of gas that dissolves in a liquid as predicted by Henry’s law.