Addition Reactions

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10 Terms

1
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hydrohalogenation

  • Mark

  • CCR possible

  • Addition of H and X (Cl,Br, or I)

  • Conditions: HCl, HBr, HI

<ul><li><p>Mark</p></li><li><p>CCR possible</p></li><li><p>Addition of H and X (Cl,Br, or I)</p></li><li><p>Conditions: HCl, HBr, HI</p></li></ul><p></p>
2
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hydration

  • Mark

  • Conditions: h2so4, h2o, h3o+

  • Addition of H and OH

<ul><li><p>Mark</p></li><li><p>Conditions: h2so4, h2o, h3o+</p></li><li><p>Addition of H and OH</p></li></ul><p></p>
3
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hydroboration-oxidation

  • Anti-Mark

  • Syn, no CC

  • Conditions: BH3 - THF, H2O2, NaOH

4
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hydrogenation

  • Syn

  • Addition of H and H

  • Conditions: H2/D2 & Pd, Pt, NI,

<ul><li><p>Syn</p></li><li><p>Addition of H and H</p></li><li><p>Conditions: H2/D2 &amp; Pd, Pt, NI, </p></li></ul><p></p>
5
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halogenation

  • Anti (inversion of stereochem)

  • Addition of X and X (Cl, Br)

  • Cyclic intermediate

  • Conditions: X2

<ul><li><p>Anti (inversion of stereochem)</p></li><li><p>Addition of X and X (Cl, Br)</p></li><li><p>Cyclic intermediate</p></li><li><p>Conditions: X2</p></li></ul><p></p>
6
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hydroxyhalogenation

  • OH is on the more substituted position

  • Anti (inversion)

  • Cyclic Intermediate

  • Adds OH and X

  • Conditions: Br2, H2O

<ul><li><p>OH is on the more substituted position</p></li><li><p>Anti (inversion)</p></li><li><p>Cyclic Intermediate</p></li><li><p>Adds OH and X </p></li><li><p>Conditions: Br2, H2O</p></li></ul><p></p>
7
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dihydroxylation - SYN

  • Syn

  • Conditions: OsO4, NMO

  • Adds OH and OH

<ul><li><p>Syn</p></li><li><p>Conditions: OsO4, NMO</p></li><li><p>Adds OH and OH</p></li></ul><p></p>
8
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dihydroxylation - ANTI

  • Anti

  • Attacks epoxide

  • Conditions: mCPBA, OH-, H2O

<ul><li><p>Anti</p></li><li><p>Attacks epoxide</p></li><li><p>Conditions: mCPBA, OH-, H2O</p></li></ul><p></p>
9
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epoxidation

  • Syn

  • Forms epoxide

  • Conditions: mCPBA

10
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ozonlysis

  • conditions: O3, DMS or Zn/H2O