Organic Chemistry II Final!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!

H2, Pd-C on Alkene

Syn Addition, Reduction of Alkene

H2, Pd-C (2 equiv.) on Alkyne

Syn Addition, Full Reduction of Alkyne

H2, Lindlar’s Cat. on Alkyne

Syn Addition, Single Reduction of Alkyne

Na, NH3 on Alkyne

Anti Addition, Single Reduction of Alkyne

1) LAH, 2) H2O on CH3-Br

Reduction of Alkyl Halide, H substituted for Br

1) LAH, 2) H2O on Epoxide

Epoxide Reduction, 3* Alcohol

RCO3H on Alkene

Epoxidation of Alkene

1) RCO3H, 2) H2O, -OH on Alkene

Anti Dihydroxylation, Anti Alcohols Added

1) OsO4, 2) NaSHO3, H2O on Alkene

Syn Dihydroxylation, Syn Alcohols Added

1) OsO4, NMO, 2) NaSHO3, H2O on Alkene

Syn Dihydroxylation, Syn Alcohols Added

KMnO4 on Alkene

Syn Dihydroxylation, Syn Alcohols Added

1) O3, 2) Zn, H2O on Alkene

Oxidative Cleavage of Alkene, Two Ketone/Aldehydes

1) O3, 2) CH3SCH3 on Alkene

Oxidative Cleavage of Alkene, Two Ketone/Aldehydes

1) O3, 2) H2O on Alkyne

Oxidative Cleavage of Alkyne, Two Carboxylic Acids

1) O3, 2) H2O on Terminal Alkyne

Oxidative Cleavage of Terminal Alkyne, Carboxylic Acid and CO2

PCC on 1* Alcohol

Oxidation to Aldehyde

HCrO4-, Amberlyst A-26 on 1* Alcohol

Oxidation to Aldehyde

CrO3, H2SO4, H2O on 1* Alcohol

Oxidation to Carboxylic Acid

PCC on 2* Alcohol

Oxidation to Ketone

CrO3 on 2* Alcohol

Oxidation to Ketone

HCrO4-, Amberylst A-26 on 2* Alcohol

Oxidation to Ketone

(CH3)3C-OOH, Ti[OCH(CH3)2]4 (DET -) on Allylic Alcohol

Epoxidation, Alcohol Pointing Up

(CH3)3C-OOH, Ti[OCH(CH3)2]4 (DET +) on Allylic Alcohol

Epoxidation, Alcohol Pointing Down