Chemistry - THERMOCHEMISTRY - Chapter 1 Terms

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2025 semester 1

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23 Terms

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thermochemistry

the study of the energy changes that accompany physical or chemical changes in matter

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energy

the ability to do work; joules (J)

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work

the amount of energy transferred by force over a distance; joules (J)

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potential energy

the energy of a body or system due to its position or composition

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kinetic energy

the energy of an object due to its motion

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thermal energy

the total quantity of kinetic and potential energy in a substance

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heat

the transfer of thermal energy from a warm object to a cooler object

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temperature

a measure of the average kinetic energy of entities in a substance

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chemical system

a group of reactants and products being studied

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surroundings

all the matter that is not part of the system

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open system

a system in which both matter and energy are free to enter and leave the system

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closed system

a system in which energy can enter and leave the system, but matter cannot

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exothermic

releasing energy to the surroundings - reactants will have more potential energy than the products

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endothermic

taking in energy from the surroundings - products will have more potential energy than the reactants

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specific heat capacity ( c )

the quantity of thermal energy required to raise the temperature of 1g of a substance by 1°C (J/g °C)

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calorimetry

the experimental process of measuring the thermal energy change in a chemical or physical change

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calorimeter

a device that is used to measure thermal energy changes in a chemical or physical change

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enthalpy (H)

the total amount of thermal energy in a substance

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enthalpy change (∆H)

the energy released to or absorbed from the surroundings during a chemical or physical change (∆H>0 endothermic, ∆H<0 exothermic)

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molar enthalpy change (∆Ht)

the enthalpy change associated with a physical, chemical, or nuclear change involving 1 mol of a substance (J/mol)

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potential energy diagram

a graphical representation of the energy transferred during a physical or chemical change

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standard enthalpy of formation (∆H°f)

the change in enthalpy that accompanies the formation of 1 mol of a compound from its elements in their standard states

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standard state

the most stable form of a substance under standard conditions, 25 °C and 100 kPa