MSCI : Chapter 5 : The Chemistry of Seawater

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53 Terms

1

What is salinity?

Grams of salt in 1 kg of water (g/kg) (ppt)

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2

What increases the density of water?

Increased dissolved salts, decreased temperatures, increased pressure

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3

What decreases the density of water?

Decreased dissolved salts, increased temperature, decreased pressure

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4

Why does saltwater have no fixed freezing point?

The salt molecules make it harder for hydrogen bonds to form between water molecules to set up the lattice structure in ice

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5

What is kind of process is conduction?

A molecular process

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6

What is conduction?

  • Heat is applied to one location and the molecules at that location transfer the energy to other molecules next to them

  • The molecules pass energy and the energy spreads relatively locally

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7

What kind of process is convection?

A fluid-based process related to density

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8

What is convection?

  • The fluid receives heat and moves to a new location taking the heat with it

  • Hydrothermal vents

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9

What kind of process is radiation?

A direct transmission of heat energy from the heat source to a substance

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10

What is radiation?

  • Radiant energy comes from the sun to the Earth

  • The sea surface receives more radiant heat than deeper waters

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11

What is light?

  • Electromagnetic radiation from the sun ad is also a wave

  • Light penetrates deeper in ocean water with fewer particles

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12

What is the relationship with particles and light penetration?

Increased particles = decreased light penetration

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13

Where is the speed of sound greater?

  • Sound travels 5x faster under water

  • Colder, saltier water = faster (more dense)

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14

What is axial modulus?

  • Describes how water compresses

  • How many molecules fit in a space and how hard it is to force them together

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15

What is the relationship between density and the speed of sound?

Increased density = increased speed of sound

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16

What is isohaline?

A line of constant salinity/similar salinity

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17

What is evaporation?

  • Liquid to Gas state change

  • Increases surface salinity

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18

What is precipitation?

  • Gas to Liquid state change

  • Decreases surface salinity

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19

What is ice formation?

  • Liquid to Solid state change

  • Sea surface salinity increases

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20

What is ice melting?

  • Solid to Liquid state change

  • Decreased surface salinity

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21

What are the Major Constituents of Seawater?

  1. Chloride

  2. Sodium

  3. Sulfate

  4. Magnesium

  5. Calcium

  6. Potassium

    They compose 99% of the salt or solid ions in seawater

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22

What is the order of the Major Constituents of Seawater from most to least abundant?

Cl > Na > SO4 > Mg > Ca > K

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23

What are conservative constituents?

  • Major dissolved ions

  • Not generally removed by biological processes

  • Low rate of chemical reactions

  • Remain in constant proportion to eachother

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24

What are non-conservative constituents?

  • Present at lower concentrations than conservative ions

  • Concentrations may be modified/are removed by biological and chemical processes

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25

What is the Principle of Constant Proportions?

Ratios between major constituents in open ocean are constant

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26

What is the Salt Cycle?

  • Method to track input and output of salt to the ocean from atmosphere and land

  • Diagramming/Quantifying the transfer of salt between these areas (ocean, atmosphere, land) and within the ocean

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27

What processes decrease ocean salinity?

  • Salt spray

  • Precipitation

  • Adsorption

    • Ions adhere to a substrate or surface and become less reactive (clay)

  • Evaporites

    • Geologic feature where salt water has been isolated on land and marine salts are still on land

  • Growth

  • Harvest

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28

What processes increase ocean salinity?

  • Excretion

  • Death

  • Hydrothermal vents and seeps

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29

What are non-conservative/biolimiting elements?

  • Concentrations change with biological and chemical reactions

  • The biolimiting nutrients (N and P)

    • Have short residence times (used often and quickly)

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30

Where are N and P at their lowest concentrations?

  • At/near surface

  • Photic zone: being consumed as fast and they are being produced

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31

Where are N and P at their highest concentration?

  • Deeper water

  • Released by decomposition, not being used by photosynthesizers

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32

What are the major gasses in seawater?

  • N2

  • O2

  • CO2

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33

Of the major gasses in seawater, which are non-conservative?

  • O2 and CO2

  • Changed by biological and chemical reactions

  • Vary spatially and temporally

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34

What is gas solubility?

  • The ability of a gas to dissolve in water

  • Changes with temperature, salinity, and pressure

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35

What is saturation concentration?

The maximum amount of that gas that the water can hold

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36

Relationship between density and gas solubility?

Increased density = increased gas solubility

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37

What are the sources/sinks of gases in seawater by Photosynthesis?

  • Sources : O2

  • Sinks : CO2

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38

What are the sources/sinks of gasses in seawater by Respiration?

  • Sources : CO2

  • Sinks : O2

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39

What are the sources/sinks of gasses in seawater by Decomposition?

  • Sources : CO2

  • Sinks : O2

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40

What are the sources/sinks of gasses in seawater by Waves?

  • Sources : CO2, O2

  • Sinks : None

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41

What is the compensation depth of gasses?

The depth at which the production and consumption of O2 and CO2 is balanced or at equilibrium

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42

What are the active reservoirs of CO2 from largest to smallest?

  1. Oceans

  2. Geological (crust)

  3. Land

  4. Atmosphere

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43

What is the pH of seawater a measure of?

H+ concentration

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44

What is an acidic water’s pH?

pH value of <7

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45

What is an alkaline/basic water’s pH?

pH value of >7

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46

What does it mean when something is acidic?

Excess H+ ions

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47

What does it mean when something is basic?

Excess OH- ions

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48

What is carbonate buffering in seawater?

The precipitation of calcium carbonate buffers the ocean’s pH

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49

Is Earth’s Heat Budget balanced or unbalanced?

Balanced

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50

What is incoming radiation?

Absorbed or reflected

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51

What is outgoing radiation?

Re-radiated back into space

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52

Where is the maximum intensity of incoming radiation at?

The equator (tropics)

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53

What happens to incoming light absorption as latitude increases?

Incoming light is more reflected as the angle increases rather than absorbed

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