Alkene Reactions

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9 Terms

1
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Hydrohalogenation: List characteristics

  • HBr, HCl, HI

  • Markovnikov addition

  • No sun or anti

2
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Halogenation: List characteristics

  • Br2, Cl2, I2

  • Anti addition (different spaces)

3
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Hydration: List characteristics

  • H2O, Acid (H+ or H2SO4)

  • Markovnikov addition: OH adds to more substituted carbon

4
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Hydroboration-Oxidation: List characteristics

  • BH3/THF ——> H2O2/NaOH

  • Anti-Markovnikov

  • Syn addition (H and OH are in same face/space)

5
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Halohydrin Formation: List characteristics

  • Br2/H2O

  • Anti addition

  • Formation of Br epoxide

6
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Epoxidation (mCPBA): List characteristics

  • Form an epoxide (three-membered ring) from Alkene

  • Syn addition

  • Oxygen (mCPBA)

7
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Oxidation Ozonolysis: List characteristics

  • O3, SMe2

  • Aldehydes added at each end of alkene

8
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Oxidation Dihydroxylation: List characteristics

  • Syn: KMnO4

  • OH at each end of Alkene

  • Anti: epoxide opening

9
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Baeyer Villiger Oxidation: List characteristics

  • mCPBA, NaOH

  • Inserting Oxygen to most substituted side of ketone