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Structural Isomerism
Same molecular formula but different structural formula
Chain isomer
Same molecular formula different arrangements of the carbon skeleton
Stereoisomers
Same structural formula but a different arrangement of atoms in a space
Rotation on double bonds
Carbon atoms in a C=C double bond and the atoms bonded to these carbons all lie in the same plane
In a C=C double bond atoms can’t rotate around them
Restricted rotation causes E/Z isomerism