Definitions of Enthalpy change (Year 13)

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18 Terms

1

ΔatHθ (Enthalpy of Atomisation)

The enthalpy change when 1 mole of gaseous atoms is formed from the element in its standard state

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2

ΔrHθ (The standard enthalpy change of reaction)

The enthalpy change when a reaction occurs in the molar quantities shown in the chemical equation

With all reactants and products in their standard states

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3

ΔcHθ (The standard enthalpy of combustion)

The enthalpy change when 1 mole of a substance is completely burned in oxygen,

under standard conditions with all reactants and products in their standard states

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4

ΔfHθ (The standard enthalpy of formation)

The enthalpy change when 1 mole of a compound is formed from its elements in their standard states under standard conditions

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5

ΔneutHθ (The standard enthalpy of neutralisation)

The enthalpy change when solutions of an acid and alkali react together to form 1 mole of water, under standard conditions

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6

ΔIE1Hθ (The first ionisation energy)

The energy needed to form 1 mole of gaseous unipositive ions from 1 mole of gaseous atoms

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7

ΔIE2Hθ (The second ionisation energy)

The energy needed to form 1 mole of gaseous dipositive ions from 1 mole of gaseous unipositive ions

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8

ΔEA1Hθ (The first enthalpy of electron affinity)

The enthalpy change when 1 mole of gaseous atoms each gain an electron to form 1 mole of gaseous uninegative ions

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9

ΔEA2Hθ (The second enthalpy of electron affinity)

The enthalpy change when 1 mole of gaseous uninegative ions each gain an electron to form 1 mole of gaseous dinegative ions

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10

ΔhydHθ (The enthalpy change of hydration)

The enthalpy change when 1 mole of gaseous ions are dissolved in water to form hydrated ions

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11

ΔsolHθ (The enthalpy change of solution)

The enthalpy change when 1 mole of solute is dissolved by a solvent

(The Solvent is nearly always water)

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12

ΔLEFHθ (The enthalpy of lattice formation/Lattice Enthalpy)

The enthalpy change when 1 mole of a solid ionic compound is formed from its gaseous ions

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13

ΔLEDHθ (The enthalpy of lattice dissociation)

The enthalpy change when 1 mole of a solid ionic compound is broken up into its constituent ions in the gas phase

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14

ΔDISHθ (The enthalpy of bond dissociation)

The enthalpy change when one mole of covalent bonds is broken in the gaseous state

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15
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Born Haber Cycle

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16

The conversion of enthalpy of atomisation to bond dissociation enthalpy

Double it

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17

The Perfect ionic model

  • All ions are completely spherical

  • all ions have an even charge distribution

  • The attractions are purely electrostatic

  • There is no covalent character in the bonds (Purely ionic)

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18

ΔLEFHθ trends within periodic table

Decreases going down the group

increases going across the period

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