Ceramic Unit Cells

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8 Terms

1
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Zinc Blende (ZnS)

- n’ = 4
- C = 4
- r-ratio: (0.225-0.414)
- cation location: tetrahedral
- structure: FCC

<p>- n’ = 4<br>- C = 4<br>- r-ratio: (0.225-0.414)<br>- cation location: tetrahedral<br>- structure: FCC</p>
2
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Rock Salt (NaCl)

- n’ = 4
- C = 6
- r-ratio: (0.414-0.732)
- cation location: octrahedral
- structure: FCC
- a = 2r+2r
- 1 anion : 1 cation

<p>- n’ = 4<br>- C = 6<br>- r-ratio: (0.414-0.732)<br>- cation location: octrahedral<br>- structure: FCC<br>- a = 2r+2r<br>- 1 anion : 1 cation</p>
3
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Cesium Chloride (CsCl)

- n’ =
- C = 8
- r-ratio: (0.732-1.0)
- cation location: cubic
- structure: cubic

<p>- n’ = <br>- C = 8<br>- r-ratio: (0.732-1.0)<br>- cation location: cubic<br>- structure: cubic</p>
4
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<p><strong>Chart</strong></p>

Chart

- Linear
- Triangular
- Tetrahedral → Zinc Blende
- Octahedral → Rock Salt
- Cubic → Cesium Chloride

5
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AmXp (Flourite CaF2)

- n’ = 4
- C(cation) = 8
- C(anion) = 4
- r-ratio: (0.225-0.414)
- cation location: cubic
- 1 anion : 2 cation

<p>- n’ = 4<br>- C(cation) = 8<br>- C(anion) = 4<br>- r-ratio: (0.225-0.414)<br>- cation location: cubic<br>- 1 anion : 2 cation</p>
6
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AmBnXp (Perovskite)

- n’ = 4
- C(cation) = 12
- C(anion) = 6
- r-ratio: (0.225-0.414)
- cation location: FCC

<p>- n’ = 4<br>- C(cation) = 12<br>- C(anion) = 6<br>- r-ratio: (0.225-0.414)<br>- cation location: FCC</p>
7
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Diamond

Same as zinc but just all diamond

<p><strong>Same as zinc but just all diamond</strong></p>
8
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Graphite

layered structure of graphene layers with van der waals forces between them

<p><strong>layered structure of graphene layers with van der waals forces between them</strong></p>