flame emission spectroscopy

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10 Terms

1
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What is flame emission spectroscopy?

It is an instrumental method used to identify metal ions and determine their concentration by analysing the light they emit when heated.

2
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What type of elements does flame emission spectroscopy detect?

Metal ions, particularly transition metals.

3
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how to identify which metal ions are present in an unknown sample

look for which metal ions have the same lines as the unknown sample does

4
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Why is flame emission spectroscopy useful?

  1. very accurate

  2. very sensitive

  3. very fast

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How is the light analysed?

The light passes through a spectroscope, which separates it into a unique line spectrum of different wavelengths.

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Why does each metal ion produce a unique line spectrum?

Because each element has a unique electron arrangement, so it emits specific wavelengths of light so leading to different observed colours

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How can flame emission spectroscopy be used to identify metal ions?

Each metal ion has a unique pattern of spectral lines, which can be matched to known reference spectra.

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How can flame emission spectroscopy determine the concentration of a metal ion?

The intensity (brightness) of the spectral lines is proportional to the concentration of the metal ion in the sample.

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What are the advantages of flame emission spectroscopy over flame tests?

  • More sensitive – can detect very small amounts of a substance.

  • More accurate – avoids errors from subjective colour observations.

  • Can analyse mixtures – unlike simple flame tests, which only show one dominant colour.

  • Very fast - can usually be automated

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Where is flame emission spectroscopy used?

  • Forensic science – identifying metals in crime scene samples.

  • Environmental monitoring – detecting metal pollution in water.

  • Industrial processes – ensuring correct metal compositions in alloys.

  • Health applications – measuring metal ions in blood samples.