Ochem Exam 1 Reactions and Reagents Alchohols
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15 Terms
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Electrophilic substitution
H3O+
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Hydride reduction with aldehydes
1)NaBH4 and ethanol (EtOH) 2)H3O+ OR use 1)LiAl4 and THF 3)H3O+
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Organometallic synthesis
1)LiX and diethyl-ether(Et2O) 2)H3O+
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Grignard Synthesis
1)RMgX and THF 2)H3O+
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Protection of OH group
Me3SiCl + triethyl-amine (Et3N) (Pterodactyl molecule)
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Conversion 1
Alkyl sulfinate and pyr
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Conversion 2
PX3 or PX5 and diethyl-ether
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Conversion 3
SOX2 and Pyr
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Dehydration
H2SO4 and heat
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ROH to Aldehyde 1
Pcc and CH2Cl2
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ROH to Aldehyde 2
1)DMSO and COCl2
2)triethyl-amine (Pterodactyl)
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ROH to Aldehyde 3
DMP and CH2Cl2
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ROH to carboxylic acid
CrO3 and H2SO4 and Acetone and H2O
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1,2 diolcleavage
HIO4 and H20
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Oxidation of a secondary alcohol
pcc chcl2
Note 
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