Organic Chemistry EAS SUB Rxns

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Last updated 4:36 PM on 8/28/26

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21 Terms

1

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<ol><li><p>KMnO4, OH-</p></li><li><p>H3O+, heat</p></li></ol><p>—————————></p><p>or Na2Cr2O7/H2SO4</p>

KMnO4, OH-
H3O+, heat

—————————>

or Na2Cr2O7/H2SO4

Benzoic Acid (Side Chain Oxidation)

<p>Benzoic Acid (Side Chain Oxidation)</p>

2

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<p>Zn(Hg), HCl, heat<br>—————————></p>

Zn(Hg), HCl, heat
—————————>

Clemensen Reduction (C=O → CH2)

<p>Clemensen Reduction (C=O → CH2)</p>

3

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<p>H2NNH2, HO-, heat</p><p>——————————></p>

H2NNH2, HO-, heat

——————————>

Wolff-Kishner reduction (C=O → CH2)

<p>Wolff-Kishner reduction (C=O → CH2)</p>

4

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<p>Zn(Hg), HCl, heat<br>—————————></p>

Zn(Hg), HCl, heat
—————————>

Clemensen Reduction (C=O → CH2)

5

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<p>H2NNH2, HO-, heat</p><p>——————————></p>

H2NNH2, HO-, heat

——————————>

Wolff-Kishner reduction (C=O → CH2)

6

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<p>EAS rxn ——></p>

EAS rxn ——>

Replaces H on benzene ring

<p>Replaces H on benzene ring</p>

7

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<p>HNO3, H2SO4</p><p>————————></p>

HNO3, H2SO4

————————>

Nitration of aromatic compounds (introduces nitro group)

<p>Nitration of aromatic compounds (introduces nitro group) </p>

8

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<p>SO3, H2SO4</p><p>————————></p>

SO3, H2SO4

————————>

Sublimation of aromatic compounds (introduces SO3H group)

<p>Sublimation of aromatic compounds (introduces SO3H group)</p>

9

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<p>X2 (X = Cl or Br)</p><p>————————></p><p>For Cl, AlCl3</p><p>For Br, FeBr3</p>

X2 (X = Cl or Br)

————————>

For Cl, AlCl3

For Br, FeBr3

Halogenation of aromatic compounds (introduces halogen group)

<p>Halogenation of aromatic compounds (introduces halogen group) </p>

10

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<p>R-Cl</p><p>————————></p><p>AlCl3</p>

R-Cl

————————>

AlCl3

Friedel-Crafts Alkylation (Introduces R group to benzene)

<p>Friedel-Crafts Alkylation (Introduces R group to benzene)</p>

11

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<p>Cl—C(=O)—R</p><p>————————></p><p>AlCl3</p>

Cl—C(=O)—R

————————>

AlCl3

Friedel-Crafts acylation of benzene (Adds an acyl group to the aromatic ring C(=O)—R)

<p>Friedel-Crafts acylation of benzene (Adds an acyl group to the aromatic ring C(=O)—R)</p>

12

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<p>CO, HCl</p><p>————————></p><p>AlCl3, CuCl</p>

CO, HCl

————————>

AlCl3, CuCl

Formylation of benzene (adds an acyl group to the aromatic ring C(=O)—R)

<p>Formylation of benzene (adds an acyl group to the aromatic ring C(=O)—R)</p>

13

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term image

Electron withdrawers (Meta Directors)

14

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term image

Electron donors (Ortho/Para directors)

15

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<p>NaNO2, HCl</p><p>(HONO)</p><p>————————></p>

NaNO2, HCl

(HONO)

————————>

Diazonium Salt

<p>Diazonium Salt</p>

16

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<p>H3PO2</p><p>————————></p>

H3PO2

————————>

Benzene ring

<p>Benzene ring</p>

17

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<p>HBF4</p><p>————————></p>

HBF4

————————>

Flouro-benzene ring

<p>Flouro-benzene ring</p>

18

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<p>H3O+ or EtOH</p><p>————————></p>

H3O+ or EtOH

————————>

Benzyl alcohol

<p>Benzyl alcohol </p>

19

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<p></p><p>KI</p><p>————————></p>

KI

————————>

benzene with iodine substituent

<p>benzene with iodine substituent</p>

20

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<p>CuCN</p><p>————————></p>

CuCN

————————>

Benzene with Nitrile substituent

<p>Benzene with Nitrile substituent</p>

21

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<p>CuBr or CuCL</p><p>————————></p>

CuBr or CuCL

————————>

Benzene with bromine or chlorine substituent

<p>Benzene with bromine or chlorine substituent</p>