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Ionization Energy
Energy required to remove an electron from a gaseous atom.
Atomic radius
Half the distance between nuclei of identical bonded atoms.
Electronegativity
An atom’s ability to attract bonding electrons.
Valence electrons
Electrons in the outermost shell available for bonding.
Cation
Positive ion formed by losing electrons.
Anion
Negative ion formed by gaining electrons.
Effective nuclear charge
More protons = stronger pull on electrons.
Shielding effect
Inner electrons block nuclear pull on valence electrons.
Distance from nucleus
More shells = electrons farther from nucleus.
Atomic radius across a period
Decreases — more protons pull electrons inward.
Atomic radius down a group
Increases — more energy levels.
Ionization energy across a period
Increases — electrons held tighter.
Ionization energy down a group
Decreases — electrons farther from nucleus.
Electronegativity across a period
Increases — stronger pull on bonding electrons.
Electronegativity down a group
Decreases — weaker pull.
Why is K⁺ smaller than K?
Loses an energy level; remaining electrons pulled closer.
Why high IE = high EN?
Strong nuclear attraction both holds electrons tightly and attracts bonding electrons.
Cations vs anions size
Cations shrink; anions expand.
More protons →
Smaller atom, higher IE, higher EN.
More shells →
Bigger atom, lower IE, lower EN.