Level 3 Organic Chem revision

Alkane → Haloalkane (Conditions + reactants)

UV light + Br2 or Cl2 (Slow)

Alkane → Haloalkane (reaction type)

Substitution reaction

Alkene → Alkane (conditions + reactants)

H2 + Heat

Alkene → Alkane (reaction type)

Elimination Reaction

Alkene → Dibromoalkane (conditions + reactants)

Br2

Alkene → Dibromoalkane (reaction type)

Addition Reaction

Alkene → Alcohol (conditions + reaction type)

H20/H+ +heat

Alkene → Alcohol (Reaction type)

Addition Reaction

Alkene → Haloalkane (conditions + reactants)

HCl (fast)

Alkene → Haloalkane (Reaction type)

Addition

Haloalkane → Amine (conditions + reactants)

NH3 , warm

Haloalkane → Amine (Reaction type)

Substitution

Haloalkane → Alkene (conditions + reactants)

Alc KOH, reflux

Haloalkane → Alkene (reaction type)

Elimination Reaction

Haloalkane → Alcohol (conditions + reactants)

Aq KOH , reflux

Haloalkane → Alcohol (Reaction type)

Substitution reaction

Alcohol → Alkene (Conditions + reactants)

Conc H2SO4 heat

Alcohol → Alkene (Reaction type)

Elimination reaction

Alcohol → Haloalkane (Conditions + reactants)

PCl3, SOCl2, Relfux

Alcohol → Haloalkane (Reaction type)

Substitution Reaction

Alcohol → Aldehyde (Conditions + reactants)

Cr2O72-/h+ cold

Alcohol → Aldehyde (Reaction type)

Oxidation Reaction

Alcohol → Carboxylic Acid (Conditions + reactants)

Cr2O72-/h+ reflux

Alcohol → Carboxylic Acid (Reaction type)

Oxidation Reaction

Aldehyde → Alcohol (Conditions + reactants)

Cr207 2- /H+ Cold

Aldehyde → Alcohol (Reactoin type)

Reduction Reaction

Aldehyde → Carboxylic Acid (conditions + reactants)

Cr207 2- /H+ Relfux

Aldehyde → Carboxylic Acid (Reaction type)

Substitution Reaction

Carboxylic Acid → Acid chloride (condition + reactants)

SOCl2, Reflux

Carboxylic Acid → Acid chloride (reaction type)

Substitution Reaction

Carboxylic Acid → Carboxylate Ion (conditions + reactants)

NH3

Carboxylic Acid → Carboxylate Ion (Reaction type)

Acid - Base reaction

Acid Chloride → Carboxylic Acid (conditions + reactants)

H20

Acid Chloride → Carboxylic Acid (reaction type)

substitution reaction

Acid Chloride → Amide (conditions + reactions)

NH3 or amine in ethanol

Acid Chloride → Amide (reaction type)

Substitution reaction

Amide → Carboxylate Ion (conditions + reactants)

NaOH

Amide → Carboxylate Ion (reaction type)

Hydrolysis

Carboxylate Ion → Amide (conditions + reactants)

heat

Carboxylate Ion → Amide (reaction type)

Substitution reaction

Ketone → Alcohol (conditions + reactants)

NaBH4

Ketone → Alcohol (reaction type)

Reduction reaction

Alcohol → Ketone (conditions + reagents)

Cr2O7 2-/H+ Reflux conditions

Alcohol → Ketone (reaction type)

Oxidation reaction

Amide → Carboxylic Acid (conditions + reagents + Other products)

H30 + (NH4 + = product)

Amide → Carboxylic Acid (reaction type)

hydrolysis reaction

Ester → Amide (conditions + reagents)

NH3 alc conditions

Ester → Amide (reaction type)

Hydrolysis reaction

Naming Prefix - Alcohol

Anol

Naming Prefix - Amine

Anamine

Naming Prefix - Carboxylic Acid

Anoic Aicd

Naming Prefix - Amide

Anamide

Naming Prefix - Ester

-yl - anoate

Naming Prefix - Aldehyde

Anal

Naming Prefix - ketone

anone

Acid Chloride

Oly Chloride

As carbon chain increases, MP/BP ___

Increases

As carbon chain increases solubility ___

Decreases

Structural Isomers (conditions for)

Same molecular formula

Geometric isomers (conditions for)

Same molecular formula & Structural formula, Must have restricted rotation

Optical Isomers (conditions for)

Must have a chiral Carbon & a racemic mix of enantiomers