3.2 ap chem properties of solids

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24 Terms

1
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What vapor pressure, melting point, and boiling point do ionic solids tend to have

Low vapor pressure, high melting point, and high boiling points

2
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What results in higher lattice energy in ionic solids

Smaller ions and/or ions with higher charges

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When do ionic solids conduct electricity

Only when the ions are mobile

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Why are ionic solids typically brittle

Due to repulsion of like charges caused by one layer sliding across another

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Why are 3d covalent network solids rigid and hard

Because the covalent bond angles are fixed

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Examples of covalent network solids

Diamond, silicon dioxide, silicon carbide, graphite

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Why do molecular solids not conduct electricity

Due to their valence electrons being tightly held within their covalent bonds and lone pairs of each molecule

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Key qualities of metallic solids

Conductivity, malleability and ductility

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Why are metallic solids conductive

Due to metallic bonds being a packed lattice of cations surrounded by a sea of moving electrons

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Ionic solid conduction state

Ionic solids are poor conductors of heat and electricity

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Molecular solids conduction state

Molecular solids are poor conductors of heat and electricity

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Covalent solid conduction state

Covalent solids are poor conductors of heat and electricity but many exceptions exist

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Metallic solid conduction state

Metallic solids are good conductors of heat and electricity

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Ionic solid relative melting point

Relatively high melting point

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Molecular solid relative melting point

Low melting point

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Covalent solid relative melting point

High melting point

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Metallic solid relative melting point

Melting point depends strongly on electron config

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Ionic solid hardness

Ionic solids are hard but brittle

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Molecular solid hardness

Molecaular solids are soft

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Covalent solid hardness

Covalent solids are very hard and brittle

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Metallic solid hardness

Metallic solids are easily deformed under stress due to ductility and malleability

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Luster of ionic, molecular, and covalent solids

Dull surface

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Luster of metallic solids

Lustrous

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Order of increasing strength of solids

Molecular solids < Ionic solids < Metallic solids < Covalent solids