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Kinetic Molecular Theory (KMT)
Kinetic- fast movement, Molecular- small (like ions and atoms), it states the at absolute zero (-273 c) or (0 k) molecules stop moving.
Is it possible in our world for it be zero kelvin anywhere.
not possible, energy everywhere
What happens if you add energy or infrared heat?
the particles move faster
what happens to molecules when something is frozen?
They move slower and are more closely packed. Molecules would theoretically stop moving zero kelvin or less.
what are the three ways for particles to move
translational movement-point a - b, rotational movement, in a circle. vibrational movement, back and forth, even solids can do this
Translational Movement
-point a - b,
Rotational Movement
Movement in the circle around the particle.
Vibrational Movement
Back and forth, even solids can do this. The more energy, the more vibrating. When you hit the max energy it turns into gas.
Three KMT phases.
Solid- locked in place, vibrate, does not follow gas laws Liquid- touching, not locked in, does not follow gas laws Gas- widely seperated
Good energy means what
Fast movement and more heat
OLd bonds v. new bonds
when old bonds are broken, energy is added, when new bonds are formed, energy is released.
Most of the time do gasses behave ideally?
yes
what works better, ideal gases or real gases
ideal gases always work better
What type of gas can condense into liquids or solids.
Only real gases
What form is an extremely cold gas.
Solid
What is the only inverse law
Boyles law, as pressure goes up, volume goes down, p1v1=p2v2
charles law
defined, v1/t1 = v2/t2
What is the average sea level in atms and mmHg
In atms it is 1.00, in mmHg it is 760
Gay Lussac Law
As temperature goes up, pressure goes up, p1/T1=P2/T2, pressure units here are mmHg
Are pressure and temperature directly or indirectly related.
Directly
Avagadros Law
As N goes up, V goes up. If the number of particles in a balloon go up then the volume goes up. V1/n1= v2/n2
Millers Law
A n goes up, p goes up. The number of particles go up only if the temp and volume are also constant.
N stands for what
Mols or particles
Combined Law
P1V1/T1N1=P2V2/T2N2, direct
If there is only one of each unit how do you solve the problem?
PV=NRT
If there is 2 of each how do you solve the problem?
Use one of the memorized formulas.
What kind of constant is R?
It is a superconstant, always the same.
What is the ideal gas law formula?
PV=NRT
What does grams always convert to?
mols
What does mmhg conver to?
atm
What type of unit is dmÂł
it is a volume unit
What type of unit is mmhg?
Pressure
What type of unit it torr?
pressure
Is n a constant?
Yes, when n is constant “the balloon has no hole”, other laws dont apply
What does n mean?
Number of moles in the gas present.
If a ballon is big, is it high or low temperature.
High
What must you add to celcius to get kelvin?
273
What units must everything be in to solve PV=NRT problems?
pressure=atm, volume=liters, N=moles, Temp.=kelvin
Pressure and the number of particles are ___related.
Always
What happens to actual particles at absolute zero?
they stop moving
Volume and pressure are _____ related.
inversely
How strong are attractions between real gas particles?
Very weak
What is the only type of movement solid molecules can do?
Vibrational
Real gases have ___ attractions that allow matter to become ____.
very weak, liquids/solids
What temperature unit does not have an abosolute scale?
celcius
When the temp is 0k what is the volume
0ml
What freezes at 0 celcius
water
If a volume is infinity, what is the pressure?
0
0 kelvin in terms of mevement means:
none
a melted ionic compound has enough energy to break what?
ionic bonds