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measure of how strongly an atom attracts electrons toward itself when it is bonded to another atom in a molecule
Electronegativity
Electronegativity ________ across the table from left to right
Increases
Electronegativity _______ down a group (top to bottom)
Decreases
most electronegative atom
Fluorine (F)
What is difference in ionic bond polarity?
Large difference (>1.7)
What is difference in polar covalent bond?
Moderate difference (0.4-1.7)
What is difference in nonpolar covalent bond?
Small difference (<0.4)
Polar molecules example
Water, dissolve well in polar solvents
Nonpolar molecules example
Fats/ oil
Explain water polarity
Oxygen is much more electronegative than hydrogen, this means oxygen pulls electrons closer to itself. Because of its uneven sharing, water molecule is a polar
Hydrogen bonding
The slight positive hydrogen (δ+) of one water molecule is attracted to the negative oxygen (δ-) of another, bond between molecules, not inside
water molecules stick to each other → surface tension
Cohesion
water sticks to other surfaces, like glass
Adhesion
Why water is a good solvent?
Water's polarity allows it to dissolve polar substances and ionic compounds
Polarity →
hydrogen bonds between molecules
What allows hydrogen bonding in DNA
N and O atoms are highly electronegative, creating partial charges that allow hydrogen bonding
Hydrophobic Effect in DNA
Nonpolar (hydrophobic) side chains cluster in the protein's interior, away from water.
This helps proteins fold into a compact shape.
Hydrophilic (Polar) Interactions in DNA
Polar (hydrophilic) side chains are usually on the outside, where they can form hydrogen bonds with water or other polar molecules
Stability & Function of polarity in DNA
Polarity helps form:
Hydrogen bonds (secondary & tertiary structure)
Ionic bonds (salt bridges between charged R-groups)
Proper folding → correct protein function (enzymes, receptors, etc.)
DNA hydrogen bonds
Polar hydrogen bonds hold A-T and G-C pairs together; nonpolar bases hide inside the helix
the energy required to remove an electron from an atom in the gaseous state
ionization energy
ionization energy across the periodic table
Increases from left to right, Decreases from top to bottom
Reason why ionization energy increases from left to right
more protons in the nucleus → stronger pull on electrons → harder to remove
Reason why ionization energy decreases from top to bottom
outer electrons are farther from nucleus + more shielding → easier to remove
Highest ionization energy element
Helium (He)
Lowest ionization energy elements
Cesium (Cs) or Francium (Fr)
First ionization energy
removing the first electron
second and third ionization energy
removing more electrons (always require more energy)
Big jumps in ionization energy show
where the atom has a stable configuration (like noble gases)
Sodium ionization energy example
1st IE: low (easy to lose 1 electron → stable Na⁺).
2nd IE: huge jump (because now you'd break into a stable inner shell).
process where bonds between atoms are broken and new bonds form, creating new substances
chemical reaction
substances that start the reaction.
reactants
substances formed
products
Synthesis (combination) chemical reaction
Two or more substances combine → one product, A + B → AB
decomposition chemical reaction
One compound breaks down → simpler substances, AB → A + B
Single Replacement chemical reaction
One element replaces another in a compound, A + BC → AC + B
Double Replacement chemical reaction
Two compounds exchange partners, AB + CD → AD + CB
Combustion (hydrocarbon + O₂) chemical reaction
Fuel + O₂ → CO₂ + H₂O (and releases energy)., CO₂ + H₂O
Energy in reactions, release energy
Exothermic
Energy in reactions, absorbs energy
Endothermic
Factors that affect speed of reactions
increase of concentration, temperature, surface area, catalysts/ enzymes
Cellular respiration =
glucose + O₂ → CO₂ + H₂O + energy (ATP).
Photosynthesis =
CO₂ + H₂O + sunlight → glucose + O₂.
Law of Conservation of Mass
Matter is not created or destroyed
Mole
022 × 10²³ particles, Avogadro's number, Moles link the atomic scale (atoms) to the lab scale (grams)
Ionic bond based on electronegativity
If atoms are very different, more or = 1.7 difference
Molar mass =
mass of 1 mole of a substance (from the periodic table)
Miles formula
Moles = grams/ moles mass
Metal + nonmetal →
Ionic bond
Nonmetal + nonmetal, same element →
Nonpolar covalent
Nonmetal + nonmetal, different elements →
Polar covalent
SO4 charge
Sulfate -2
NO3 charge
Nitrate -1
OH charge
Hydroxide -1
CO3 charge
Carbonate -2
PO4 charge
Phosphate -3