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Vocabulary and reaction mechanism details for various alkene additions, including reagents and regioselectivity.
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Hydrohalogenation
The reaction of an alkene + H−X where X={a,Br,1}.
Catalytic Hydrogenation
The addition of H2 to an alkene using a metal catalyst, which involves syn addition and can result in a meso compound or an enantiomer.
Halogenation, halhydrin formation
A process involving nucleophilic attack (nucattack) with X2 and H2O to create a substituted alkene.
Acid-catalyzed hydration of alkenes
A three-step mechanism: 1. Pronate (H3O+), 2. attack, 3. depronate.
Oxymercuration-Demercuration
A reaction using Hg(OAc)2 that results in no rearrangement.
Hydroboration Oxydation
A reaction using reagents BH3⋅THF and H2O2,NaOH that places an OH group on the less substituted position (anti-Mark).