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What is electromotive force (emf)?
Electrical energy per unit charge produced by a source
What is the unit of emf?
V
Equation linking emf, charge and energy
E= Qε
What is internal resistance?
loss of pd per unit current in the source when current passes through source
Why is terminal pd less than emf?
Energy is lost as heat due to internal resistance
What is the formula relating emf and internal resistance?
ε=IR+Ir
What does ε=IR+Ir represent?
Emf equals terminal pd plus lost pd
How is current related to emf and total resistance?
I=ε/(R+r)
What is lost pd?
Pd across internal resistance equal to Ir
What is the power supplied by the cell?
P=I2R+I2r
When is maximum power delivered to a load?
When load resistance equals internal resistance,
R=r
How can terminal pd be measured?
Using a high-resistance voltmeter across cell terminals
Why does terminal pd decrease with increasing current?
More current increases lost pd across internal resistance
What is the gradient of a V-I graph?
Negative gradient equal to
−r
What is the y-intercept of a V-𝐼 graph?
The emf of the cell
How is internal resistance calculated from two current-pd pairs?
r=(V1−V2)/(I2−I1)
What happens to terminal pd at zero current?
Terminal pd equals emf since no energy is lost
How is internal resistance shown in a circuit?
As a resistor in series with the cell
Why is matching load resistance important?
Maximizes power transfer by ensuring
R=r
What factors affect internal resistance?
Material properties, temperature, and age of the cell
How does increasing current affect efficiency?
Efficiency decreases as lost pd increases with higher current
What is the physical origin of internal resistance?
Opposition due to ion movement and material resistivity within the cell
Why is emf constant but terminal pd variable?
Emf depends on chemical energy, while terminal pd depends on current
How is power wasted in a cell?
P wasted=I2 r, energy dissipated as heat in internal resistance
Explain why terminal pd decreases as current increases.
Higher current causes greater lost pd across internal resistance
Why does a graph of V vs. I have a negative gradient?
The internal resistance
r reduces terminal pd as current increases
What is the condition for maximum power transfer in a circuit?
Load resistance equals internal resistance,
R=r
Why does terminal pd equal emf when no current flows?
No energy is lost in internal resistance at zero current