Chemistry of the Atmosphere and Climate Change

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138 Terms

1

Atmosphere Composition

99% nitrogen and oxygen near Earth's surface.

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2

Non-Uniform Gas Distribution

Gas composition varies with altitude and location.

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3

Troposphere

Lowest atmospheric layer; where weather occurs.

<p>Lowest atmospheric layer; where weather occurs.</p>
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4

Stratosphere

Second layer; contains ozone layer absorbing UV-B.

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5

Mesosphere

Middle layer; meteors burn up here.

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6

Thermosphere

Upper atmosphere; very few molecules present.

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7

Solar Wind

Charged particles emitted from the Sun.

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8

Auroras

Light displays formed in the thermosphere.

<p>Light displays formed in the thermosphere.</p>
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9

Particle Collisions

Electrons excite atmospheric molecules, emitting light.

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10

Red Auroras

Above 200 km; caused by oxygen molecules.

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11

Blue Auroras

100-200 km; caused by nitrogen molecules.

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12

Green Auroras

100-200 km; caused by oxygen molecules.

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13

Pink Auroras

Below 100 km; caused by nitrogen molecules.

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14

Photodissociation

Chemical bond rupture from photon absorption.

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15

Photoionization

Molecule absorbs radiation, ejects electron, becomes ion.

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16

Ionization Energy

Energy needed to remove an electron from an atom.

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17

Wavelength (λ_max)

Maximum wavelength for ionization of specific molecules.

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18

O2 Dissociation Energy

498 kJ/mol required to break O2 bond.

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19

Planck's Equation

E=hν relates energy to photon frequency.

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20

Speed of Light Equation

c=λν relates speed, wavelength, and frequency.

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21

Avogadro's Number

6.022 x 10^23; used for mole calculations.

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22

Ultraviolet Radiation

Short wavelength radiation; can cause ionization.

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23

Ozone Layer

Protective layer absorbing harmful UV radiation.

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24

Meteors

Burn up in the mesosphere due to friction.

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25

Excited Atoms

Atoms with electrons in higher energy states.

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26

Aurora Formation Process

Involves solar wind, collisions, and light emission.

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27

Reactive Oxygen

Oxygen's lower bond enthalpy makes it more reactive.

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28

Ion Presence

Enables long-range radio communication in the atmosphere.

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29

Ozone Layer

Protective gas ring absorbing harmful UV rays.

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30

Stratosphere

Layer of atmosphere where ozone layer is located.

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31

Ozone Thickness

2 to 8 mm under normal conditions.

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32

UVA Rays

Most common UV rays causing skin aging.

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33

UVB Rays

Causes sunburns, cataracts; 95% absorbed by ozone.

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34

UVC Rays

Most dangerous UV rays; 100% absorbed by ozone.

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35

Photokeratitis

Eye injury caused by UV radiation exposure.

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36

Ozone Absorption Range

Ozone absorbs radiation between 240 and 310 nm.

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37

Ozone Formation

Occurs through O₂ and free oxygen atom reaction.

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38

Photodissociation

Process where UV radiation splits oxygen molecules.

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39

Chemical Reaction for Ozone

O + O₂ → O₃ forms ozone.

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40

Ozone Depletion Discovery

1974 discovery of CFCs harming ozone by Rowland and Molina.

<p>1974 discovery of CFCs harming ozone by Rowland and Molina.</p>
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41

CFCs

Chlorofluorocarbons used in aerosols and refrigerants.

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42

HCFCs

Hydrochlorofluorocarbons; less harmful than CFCs.

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43

Halon

Used in fire extinguishers; ozone-depleting chemical.

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44

Methyl Bromide

Pesticide contributing to ozone depletion.

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45

Ozone Depletion Process

CFCs release chlorine, which reacts with ozone.

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46

Chlorine Monoxide

Product of ozone breakdown by chlorine.

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47

Ozone Hole

Area of severe ozone depletion, notably over Antarctica.

<p>Area of severe ozone depletion, notably over Antarctica.</p>
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48

Dobson Unit (DU)

Standard measurement for ozone concentration; 1 DU = 0.01 mm.

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49

Ozone Hole Monitoring

NASA tracks ozone hole size and extent.

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50

UV Radiation Effects

Increased exposure leads to skin cancer and eye damage.

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51

Ozone Layer Importance

Shields life from harmful UV radiation.

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52

Ozone Depletion Impact

Affects ecosystems, increases health risks.

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53

Ozone Layer Shielding

Critical for protecting life from UV radiation.

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54

UV Radiation Types

Includes UVA, UVB, and UVC with varying effects.

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55

Ozone Layer Environmental Concern

Depletion allows more harmful UV radiation to reach Earth.

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56

Ozone Formation Process Steps

UV radiation splits O₂, forming ozone through collisions.

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57

CFCs

Chlorofluorocarbons that deplete ozone layer.

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58

UV radiation

Ultraviolet light causing CFC bond breakage.

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59

Chlorine atoms

Released from CFCs, react with ozone.

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60

Ozone (O₃)

Ozone layer protects Earth from UV radiation.

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61

Chlorine monoxide (ClO)

Intermediate product in ozone depletion cycle.

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62

Montreal Protocol

1987 agreement to phase out CFCs.

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63

Troposphere

Lowest atmospheric layer, contains weather.

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64

Carbon dioxide (CO₂)

Greenhouse gas from organic matter decomposition.

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65

Carbon monoxide (CO)

Toxic gas from incomplete combustion.

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66

Methane (CH₄)

Greenhouse gas from organic matter decomposition.

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67

Nitric oxide (NO)

Pollutant from combustion engines and discharges.

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68

Ozone (O₃) in troposphere

Harmful pollutant, differs from stratospheric ozone.

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69

Sulfur dioxide (SO₂)

Gas from burning fossil fuels, contributes to acid rain.

<p>Gas from burning fossil fuels, contributes to acid rain.</p>
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70

Acid rain

Precipitation containing sulfuric or nitric acids.

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71

Sulfur trioxide (SO₃)

Forms from oxidation of sulfur dioxide.

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72

Sulfuric acid (H₂SO₄)

Result of SO₃ reacting with water.

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73

Calcium carbonate (CaCO₃)

Limestone used in reducing SO₂ emissions.

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74

Calcium oxide (CaO)

Product of heating limestone, reacts with SO₂.

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75

Calcium sulfite (CaSO₃)

Formed from CaO and SO₂ reaction.

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76

Scrubber system

Aqueous suspension removing CaSO₃ from emissions.

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77

Nitrogen oxides (NOₓ)

Pollutants contributing to photochemical smog.

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78

Photochemical smog

Smog formed from sunlight-driven reactions.

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79

Nitrogen dioxide (NO₂)

Main component of urban smog haze.

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80

Smog

Mix of smoke and fog, worsened by weather.

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81

Greenhouse effect

Trapping of heat by greenhouse gases.

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82

Respiratory issues

Health problems linked to air pollution.

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83

Pollutants

Substances causing environmental harm.

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84

Decomposition

Breakdown of organic matter releasing gases.

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85

NO₂

Nitrogen dioxide, key in ozone formation.

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86

O₃

Ozone, a pollutant formed from NO₂.

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87

Respiratory Issues

Health problems like asthma and lung damage.

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88

Visibility Reduction

Decreased sight due to air pollution.

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89

Ecosystem Damage

Harm to plants and natural habitats.

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90

Catalytic Converters

Devices reducing NOₓ emissions in vehicles.

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91

Public Transport

Shared transport options to lower fossil fuel use.

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92

Electric Vehicles

Cars powered by electricity, reducing emissions.

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93

Industrial Smog

Grayish pollution from burning coal or oil.

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94

Photochemical Smog

Brownish pollution from vehicle emissions and sunlight.

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95

London Smog

Historical industrial smog associated with London.

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96

L.A. Smog

Smog formed in Los Angeles from vehicles.

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97

Sulfur Oxides (SO₂)

Main pollutants in industrial smog.

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98

Nitrogen Oxides (NOₓ)

Key pollutants in photochemical smog.

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99

Greenhouse Effect

Atmospheric phenomenon retaining Earth's heat.

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100

Carbon Dioxide (CO₂)

Major greenhouse gas from fossil fuel combustion.

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