IR Spectroscopy Functional Groups, IR Spectroscopy

IR Spectrum Range of Functional Group Bond:

alkane C-H (sp^3)

Shape? Intensity?

2850-3000 cm-1

Shape: often strong

IR Spectrum Range of Functional Group Bond:

1/2. Alkene C-H (sp^2)

Shape? Intensity?

3000-3100 cm-1

Shape: sharp

Intensity: medium

IR Spectrum Range of Functional Group Bond:

1/2. alkyne C-H (sp)

Shape? Intensity?

3300 cm-1

Shape: sharp

Intensity: medium

IR Spectrum Range of Functional Group Bond:

2/2. Alkene C=C

Shape? Intensity?

1600-1650 cm-1

Shape: sharp

Intensity: medium

IR Spectrum Range of Functional Group Bond:

aromatic C=C

Shape? Intensity?

1475-1600 cm-1

Shape: sharp

Intensity: medium

IR Spectrum Range of Functional Group Bond:

2/2. alkyne C=C

Shape? Intensity?

2100-2200 cm-1

Shape: sharp

Intensity: medium-weak

IR Spectrum Range of Functional Group Bond:

Nitrile C=N

Shape? Intensity?

2200-2300 cm-1

Shape: broad

Intensity: medium

IR Spectrum Range of Functional Group Bond:

Alcohol O-H

Shape? Intensity?

3300 cm-1

Shape: broad, smooth

Intensity: strong

IR Spectrum Range of Functional Group Bond:

Amine N-H

Shape? Intensity?

3300 cm-1

Shape: medium

Intensity: broad

IR Spectrum Range of Functional Group Bond:

1/2. Ester C=O

Shape? Intensity?

1740 cm-1

Shape:

Intensity: strong

IR Spectrum Range of Functional Group Bond:

2/2. Ester C-O

Shape? Intensity?

1000-1300 cm-1

Shape: Often two bands

Intensity: strong

IR Spectrum Range of Functional Group Bond:

1/2. aldehyde C=O

Shape? Intensity?

1730 cm-1

Shape: strong

Intensity: -

IR Spectrum Range of Functional Group Bond:

2/2. aldehyde H-CO

Shape? Intensity?

2700, 2800 cm-1

Shape: medium

Intensity: -

IR Spectrum Range of Functional Group Bond:

ketone C=O

Shape? Intensity?

1720 cm-1

Shape: strong

Intensity: -

IR Spectrum Range of Functional Group Bond:

1/2. carboxylic acid C=O

Shape? Intensity?

1710 cm-1

Shape: strong

Intensity: -

IR Spectrum Range of Functional Group Bond:

2/2. carboxylic acid O-H

Shape? Intensity?

2500-3500 cm-1

Shape: jagged

Intensity: very broad

IR Spectrum Range of Functional Group Bond:

1/2. amide C=O

Shape? Intensity?

1650 cm-1

Shape: broad

Intensity: strong

IR Spectrum Range of Functional Group Bond:

2/2. amide N-H

Shape? Intensity?

3300 cm-1

Shape: broad

Intensity: strong

IR Spectrum Range of Functional Group Bond:

1/2. alkyl halide C-Cl

Shape? Intensity?

600-800 cm-1

Shape: Strong

Intensity: Strong

IR Spectrum Range of Functional Group Bond:

2/2. alkyl halide C-Br

Shape? Intensity?

500- 600 cm-1

Shape: Strong

Intensity: Strong

IR Spectrum analysis steps (1-5)

1. Distinguish C-H stretches of alkanes, alkenes, and alkynes by their position relative to ________

3000 cm-1

IR Spectrum analysis steps (1-5)

2. A sharp peak at ____-____cm-1 suggests a C=C stretch

1600-1650 cm-1

IR Spectrum analysis steps (1-5)

3. Look at _____cm-1 for O-H and N-H stretches (carboxylic acid O-H stretches occur over a broader range of 2500-3500 cm-1)

3300 cm-1

IR Spectrum analysis steps (1-5)

4. Bands near _____ cm-1 suggest a triple bond

2200 cm-1

IR Spectrum analysis steps (1-5)

5. A strong band in the ____-____ cm-1 region indicates a carbonyl

1650-1800 cm-1

Key principle in IR:

The (a) ______ of IR bands in a spectrum often tells us just as much as their (b) _______.

a. absence

b. presence

IR diagnostic or characteristic region range

____-____ cm-1

4000-1500 cm-1

IR fingerprint region range:

____-____ cm-1

1500-400 cm-1

Hooke's Law: Bond strength is directly proportional to the frequency, so (a) _______ bonds vibrate (b) _______ and absorb IR light of (c) _______ frequency.

Bond strength is directly proportional to the frequency, so (a) stronger bonds vibrate (b) faster and absorb IR light of (c) higher frequency.

According to Hooke's Law, reduced mass is indirectly proportional to the frequency, so bonds with (a)_______ atoms vibrate (b)________ and absorb IR light of (c)________ frequency

According to Hooke's Law, reduced mass is indirectly proportional to the frequency, so bonds with (a) lighter atoms vibrate (b) faster and absorb IR light of (c) higher frequency