Ch 22 Reactions Orgo II

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29 Terms

1
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<p>Primary alcohol</p>

Primary alcohol

What is the product of the reaction between an acid chloride reacted with NaBH4 (1st step) and H3O+ (2nd step)

<p>What is the product of the reaction between an acid chloride reacted with NaBH4 (1st step) and H3O+ (2nd step)</p>
2
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<p>Primary alcohol + COOHR’</p>

Primary alcohol + COOHR’

What is the product of the reaction between an acid anhydride reacted with NaBH4 (1st step) and H3O+ (2nd step)?

<p>What is the product of the reaction between an acid anhydride reacted with NaBH4 (1st step) and H3O+ (2nd step)?</p>
3
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<p>Primary alcohol + HOR’</p>

Primary alcohol + HOR’

What is the product of the reaction between an ester reacted with NaBH4 and EtOH?

<p>What is the product of the reaction between an ester reacted with NaBH4 and EtOH?</p>
4
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No reduction

What is the product of the reaction between a carboxylic acid and NaBH4?

<p>What is the product of the reaction between a carboxylic acid and NaBH4?</p>
5
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No reduction

What is the product of a reaction between an amide and NaBH4?

<p>What is the product of a reaction between an amide and NaBH4?</p>
6
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<p>Primary alcohol</p>

Primary alcohol

What is the product of a reaction between acid chloride, and LiAlH4 (1st step) and H3O+ (2nd step)?

<p>What is the product of a reaction between acid chloride, and LiAlH4 (1st step) and H3O+ (2nd step)?</p>
7
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<p>Primary alcohol</p>

Primary alcohol

What is the product of the reaction between an acid anhydride and LiAlH4 (1st step) and H3O+ (2nd step)?

<p>What is the product of the reaction between an acid anhydride and LiAlH4 (1st step) and H3O+ (2nd step)?</p>
8
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<p>Primary alcohol and HOR’</p>

Primary alcohol and HOR’

What is the product of the reaction between an ester and LiAlH4 (1st step) and H3O+ (2nd step)?

<p>What is the product of the reaction between an ester and LiAlH4 (1st step) and H3O+ (2nd step)?</p>
9
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<p>Primary alcohol</p>

Primary alcohol

What is the product of the reaction between a carboxylic acid and LiAlH4 (1st step) and H3O+ (2nd step)?

<p>What is the product of the reaction between a carboxylic acid and LiAlH4 (1st step) and H3O+ (2nd step)?</p>
10
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<p>Amine</p>

Amine

What is the product of the reaction between an amide and LiAlH4 (1st step) and H2O (2nd step)?

<p>What is the product of the reaction between an amide and LiAlH4 (1st step) and H2O (2nd step)?</p>
11
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<p>Ester</p>

Ester

What is the product of the reaction between an ester and NaOR'“?

<p>What is the product of the reaction between an ester and NaOR'“?</p>
12
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<p>Ester</p>

Ester

What is the product of the reaction between an acid chloride and LiOR’?

<p>What is the product of the reaction between an acid chloride and LiOR’?</p>
13
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<p>Ester</p>

Ester

What is the product of the reaction between an acid anhydride and NaOR’?

<p>What is the product of the reaction between an acid anhydride and NaOR’?</p>
14
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<p>Amide</p>

Amide

What is the product of the reaction between an ester and LiNR2”?

<p>What is the product of the reaction between an ester and LiNR2”?</p>
15
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<p>Carboxylic acid</p>

Carboxylic acid

What is the product of the reaction between an ester and NaOH (1st step) and HCl (2nd step)?

<p>What is the product of the reaction between an ester and NaOH (1st step) and HCl (2nd step)?</p>
16
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<p>Carboxylic acid</p>

Carboxylic acid

What is the product of the reaction between an amide and NaOH (1st step) and HCl (2nd step)?

<p>What is the product of the reaction between an amide and NaOH (1st step) and HCl (2nd step)?</p>
17
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<p>Primary amine</p>

Primary amine

What is the product of the reaction between a phthalimide and KOH/EtOH (1st step), and RBR (2nd step), and KOH/H2O (3rd step)?

<p>What is the product of the reaction between a phthalimide and KOH/EtOH (1st step), and RBR (2nd step), and KOH/H2O (3rd step)?</p>
18
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<p>Primary alcohol</p>

Primary alcohol

What is the product of the reaction between acid chloride and NaBH4 or LiAlH4 (1st step) and HCl (2nd step)?

<p>What is the product of the reaction between acid chloride and NaBH4 or LiAlH4 (1st step) and HCl (2nd step)?</p>
19
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<p>Primary alcohol</p>

Primary alcohol

What is the product of the reaction between an acid anhydride and NaBH4 or LiAlH4 (1st step) and HCl (2nd step)?

<p>What is the product of the reaction between an acid anhydride and NaBH4 or LiAlH4 (1st step) and HCl (2nd step)?</p>
20
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<p>Primary alcohol</p>

Primary alcohol

What is the product of the reaction between an ester and NaBH4 or LiAlH4 (1st step) and HCl (2nd step)?

<p>What is the product of the reaction between an ester and NaBH4 or LiAlH4 (1st step) and HCl (2nd step)?</p>
21
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<p>Primary alcohol</p>

Primary alcohol

What is the product of the reaction between a carboxylic acid and LiAlH4 (1st step) and HCl (2nd step)?

<p>What is the product of the reaction between a carboxylic acid and LiAlH4 (1st step) and HCl (2nd step)?</p>
22
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<p>Amine</p>

Amine

What is the product of the reaction between an amine and LiAlH4 (1st step) and ether (2nd step)?

<p>What is the product of the reaction between an amine and LiAlH4 (1st step) and ether (2nd step)?</p>
23
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<p>Aldehyde</p>

Aldehyde

What is the product of the reaction between an acid chloride and LiAlH(O-t-Bu)3 (-75 degrees Celsius)?

<p>What is the product of the reaction between an acid chloride and LiAlH(O-t-Bu)3 (-75 degrees Celsius)?</p>
24
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<p>Aldehyde</p>

Aldehyde

What is the product of the reaction between an ester and DIBAH (-78 degrees Celsius) (1st step), and HCl (2nd step)

<p>What is the product of the reaction between an ester and DIBAH (-78 degrees Celsius) (1st step), and HCl (2nd step)</p>
25
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<p>Carboxylic acid</p>

Carboxylic acid

What is the product of the reaction between a methyl ketone and X2 (excess), NaOH (1st step) and HCl (2nd step)?

<p>What is the product of the reaction between a methyl ketone and X2 (excess), NaOH (1st step) and HCl (2nd step)?</p>
26
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<p>Tertiary alcohol</p>

Tertiary alcohol

What is the product of the reaction between an acid chloride and R-Li or R-MgX (1st step) and HCl (2nd step)?

<p>What is the product of the reaction between an acid chloride and R-Li or R-MgX (1st step) and HCl (2nd step)?</p>
27
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<p>Tertiary alcohol</p>

Tertiary alcohol

What is the product of the reaction between an acid anhydride and R’-Li or R’-MgX (1st step) and HCl (2nd step)?

<p>What is the product of the reaction between an acid anhydride and R’-Li or R’-MgX (1st step) and HCl (2nd step)?</p>
28
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<p>Tertiary alcohol</p>

Tertiary alcohol

What is the product of the reaction between an ester and R’-Li or R’-MgX (1st step) and HCl (2nd step)?

<p>What is the product of the reaction between an ester and R’-Li or R’-MgX (1st step) and HCl (2nd step)?</p>
29
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<p>Ketone</p>

Ketone

What is the product of the reaction between acid chloride and R’2-CuLi?

<p>What is the product of the reaction between acid chloride and R’2-CuLi?</p>