Periodic Variations: Electron Affinity and Electronegativity

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30 Terms

1

Electron Affinity

It is the ability of an atom to accept an electron

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2

Electron Affinity

Unlike electronegativity, This is a quantitative measurement of the energy change that occurs when an electron is added to a neutral gas atom.

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3

Higher an Atoms Affinity for Electrons

The more negative the electron affinity value, the _____________________________.

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4

Decreases Down a Group of Elements

Electron Affinity generally _______________ because each atom is larger than the atom above it.

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5

Electron Affinity

This means that an added electron is further away from the atom's nucleus compared with its position in the smaller atom.

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6

Relatively Weaker

In Electron Affinity, With a larger distance between the negatively-charged electron and the positively-charged nucleus, the force of attraction is __________________

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7

Electron Affinity Increases from left to Right within a Period

This is caused by the decrease in atomic radius.

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8

Electron Affinity Increases from left to Right within a Period, Electron Affinity Decreases from Top to Bottom within a Group

What are the Notes in Electron Affinity?

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9

Electron Affinity Decreases from Top to Bottom within a Group

This is caused by the increase in atomic radius.

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10

Electronegativity

It can be understood as a chemical property describing an atom's ability to attract and bind with electrons

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11

Electronegativity

It is a qualitative property, there is no standardized method for calculating this

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12

Pauling Scale

It is the most common scale for quantifying electronegativity

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13

Pauling Scale

It named after the chemist Linus Pauling

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14

Linus Pauling

Who made the Pauling Scale

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15

Pauling Scale

The numbers assigned by the This are dimensionless due to the qualitative nature of electronegativity.

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16

Electronegativity Values

This for each element can be found on certain periodic tables.

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17

Electronegativity

It measures an atom's tendency to attract and form bonds with electrons.

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18

Electronic Configuration of Atoms

Electronegativity measures an atom's tendency to attract and form bonds with electrons. This property exists due to the What?

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19

Octet Rule

Most atoms follow what rule which having the valence, or outer, shell comprise of 8 electrons

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20

generally lose electrons

the elements on the left side of the periodic table ____________________ when forming bonds

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21

more energy efficient in gaining electrons

elements on the right side of the periodic table are __________________________ to create a complete valence shell of 8 electrons.

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22

nature of electronegativity

It is effectively described the more inclined an atom is to gain electrons, the more likely that atom will pull electrons toward itself.

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23

electronegativity increases from left to right across a period of elements

If the valence shell of an atom is less than half full, it requires less energy to lose an electron than to gain one. Conversely, if the valence shell is more than half full, it is easier to pull an electron into the valence shell than to donate one.

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24

electronegativity increases from left to right across a period of elements, Electronegativity decreases from top to bottom down a group, Important exceptions of the above rules include the noble gases, lanthanides, and actinides, As for the transition metals

What are the Notes in Electronegativity?

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25

Electronegativity decreases from top to bottom down a group

This is because atomic number increases down a group, and thus there is an increased distance between the valence electrons and nucleus, or a greater atomic radius

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Important exceptions of the above rules include the noble gases, lanthanides, and actinides

The noble gases possess a complete valence shell and do not usually attract electrons. The lanthanides and actinides possess more complicated chemistry that does not generally follow any trends. Therefore, noble gases, lanthanides, and actinides do not have electronegativity values.

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27

As for the Transition Metals

although they have electronegativity values, there is little variance among them across the period and up and down a group. This is because their metallic properties affect their ability to attract electrons as easily as the other elements.

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28

Noble Gases, Lanthanides, Actinides

What are the Important exceptions of the above rules in Electronegativity?

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29

Electron Affinity

The amount of energy released when the atom gains an electron

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30

Electronegativity

The general tendency of the electron of the atom to attract electrons toward itself in a compound

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