Organic Chemistry 1 Reactions - Alkenes

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18 Terms

1
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Halogenation

X2

<p>X2</p>
2
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Halohydrins - trans version 1

X2, H2O

<p>X2, H2O</p>
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Halohydrins - trans version 2

NBS, H2O, DMSO

<p>NBS, H2O, DMSO</p>
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Hydrations - markovnikov version 1

H2SO4 OR H3PO4, H2O

<p>H2SO4 OR H3PO4, H2O</p>
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Oxymercuration/Demercuration - Markovnikov

Hg(OAc)2, H2O then NaBH4

<p>Hg(OAc)2, H2O then NaBH4</p>
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Hydroboratoin - Oxidation - anti-markovnikov

BH3, THF then H2O2, OH-

<p>BH<sub>3</sub>, THF then H<sub>2</sub>O<sub>2</sub>, OH<sup>- </sup></p>
7
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Epoxides from halohydrins version 1

NaOH (base), H2O

<p>NaOH (base), H2O</p>
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Epoxides creation (no halohydrins)

mCPBA, CH2Cl2

<p>mCPBA, CH2Cl2</p>
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Epoxide opening - trans

Acid

<p>Acid</p>
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Expoxide opening - syn version 1

OsO4/Pyridine, NaSO3/H2O

<p>OsO4/Pyridine, NaSO3/H2O</p>
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Expoxide opening - syn version 2

OsO4/Acetone/H2O, NMO

<p>OsO4/Acetone/H2O, NMO</p>
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Oxidative cleavages version 1

O3, Zn/H3O+

<p>O3, Zn/H3O+</p>
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Oxidative cleavages version 2

KmnO4, H3O+

<p>KmnO4, H3O+</p>
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Catalytic hydrogenation - cis

h2, metal

<p>h2, metal</p>
15
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Simmons-smith

CH2I2, Zu(Cu)/ether

<p>CH2I2, Zu(Cu)/ether</p>
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Carbene addition

CHCl3, KOH

<p>CHCl3, KOH</p>
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Dehydrohalogenation

KOH, CH3CH2OH/ethanol

<p>KOH, CH3CH2OH/ethanol</p>
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Dehydration

H2SO4/H20, THF

<p>H2SO4/H20, THF</p>