Chemistry of the atmosphere

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53 Terms

1

for 200 million years…..

the proportions of diff gases in the the atmosphere have been much the same as they are today

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2

The proportions of different gases in the atmosphere- nitrogen

about four-fifths (approximately 80%) nitrogen

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3

The proportions of different gases in the atmosphere- oxygen

about one-fifth (approximately 20%) oxygen

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4

The proportions of different gases in the atmosphere- other gases

small proportions of various other gasws- including carbon dioxide, water vapour and noble gases

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5

why is evidence for earth’s early atmosphere limited

due to the time scale of 4.6 billion years so theories have changed over time

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6

one theory suggests that during first billions of years

  • there was intense volcanic activity that released gases that formed the early atmosphere

    • like water vapour- as the earth cooled water vapour condensed to form oceans

    • volcanoes also released a lot of carbon dioxide- also small amounts of methane and ammonia- and nitrogen which gradually built up

  • at start of period atmosphere was most like mars or venus today- mainly CO2 and little to no O2

    • CO2 dissolved in water and carbonates were precipitated producing sediments, reducing amount of CO2 in atmosphere

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7

how oxygen increased in the atmosphere

  • photosynthetic plants in sea 2.7 billion years ago- algae and plants

    • photosynthesis produced oxygen

    • plants evolved meaning more O2 could be produced- reached point where animals could evolve

    • photosynthesis also takes in CO2- carbon trapped in fossil fuels

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8

how long does it take fossil fuels to form

millions of years

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9

are fossil fuels non renewable or renewable

non renewable- if we keep using them, they will run out

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10

how is coal formed

  • from remains of ferns and trees

    • if they die in marshy wetlands then they don’t decompose- due to lack of O2 and acidic conditions- both prevent decomposition from happenening

  • over time plants are covered by sedimentary rocks- the pressure and high temp creates coal

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11

how is oil formed?

  • crude oil is formed from plankton who were covered by mud on sea bed- if O2 isnt present then they don’t decompose

    • over time, they are compressed by sediment

      • heat and pressure convert them into crude oil

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12

how is natural gas formed??

  • mainly the hydrocarbon methane, often find natural gas near deposits of oil

    • natural gas formed in similar way as oil- crude oil

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13

examples of greenhouse gases

water vapour, methane and carbon dioxide

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14

Amount of water vapour in the atmosphere….

..varies widely and changes depending on the temp

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15

How the greenhouse effect works?

  1. Energy from the sun travels to the earth as short wave radiation e.g. ultra violet & visible light

  2. Some of radiation reflects back into space but most pases through easily as short wavelength radiation doesnt interact strongly with gas molecules

  3. Energy of radiation is absorbed when it reaches the surface of earth

  4. Surface of earth now radiates the energy as long wavelength radiation e.g. infra red

  5. Some of LWR interacts with greenhouse gas molecules- energy in LWR is absorbed- as energy trapped in atmosphere causes temp to increase

<ol><li><p>Energy from the sun travels to the earth as short wave radiation e.g. ultra violet &amp; visible light</p></li><li><p>Some of radiation reflects back into space but most pases through easily as short wavelength radiation doesnt interact strongly with gas molecules</p></li><li><p>Energy of radiation is absorbed when it reaches the surface of earth</p></li><li><p>Surface of earth now radiates the energy as long wavelength radiation e.g. infra red</p></li><li><p>Some of LWR interacts with greenhouse gas molecules- energy in LWR is absorbed- as energy trapped in atmosphere causes temp to increase</p></li></ol>
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16

Why is the greenhouse effect key?

  • Keeps temp warm enough to support life

  • Without greenhouse effect, the earth would be too cold for most living organisms to survive

<ul><li><p>Keeps temp warm enough to support life</p></li><li><p>Without greenhouse effect, the earth would be too cold for most living organisms to survive</p></li></ul>
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17

are the levels of CO2 and methane increasing/decreasing and why?

  • levels are increasing due to human activity

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18

Why are CO2 levels increasing??

  • burning of fossil fuels

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19

What do we use coal for and what does it produce?

  • for electricity, produces CO2

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20

What do we use petrol & diesel for and where does it come from??

  • power cars

  • Came from burning fossil fuels producing CO2

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21

What do we use natural gas for and where does it come from??

  • heat our homes

  • Came from fossil fuels, burnt to produce CO2

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22

Where is CO2 normally absorbed from??

  • growing trees

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23

Why have the levels of CO2 being absorbed decreased?

  • rainforests are being destroyed by deforestation

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24

Why is deforestation occuring and how??

  • forests burned to supply land for burning cattle

  • Release large amounts of CO2

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25

Why is temp of atmosphere increasing?

More of the energy from the sun is trapped

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26

Effects of rising temps

  • melting of polar ice sheets and glaciers

  • Lead to more severe weather

  • change distribution of animals

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27

Effects of rising temps- melting of ice

  • leads to rising sea levels- flooding of low lying areas

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28

Effects of rising temps- severe weather

  • storms in the uk

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29

Effects of rising temps- distribution of animals

  • such as insects—> may change distribution of insect borne diseases e.g. malaria

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30

What do scientists believe climate change is caused by?

  • human activity which causes release of greenhouse gases

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31

Evidence for climate change

Shared between many different scientists- can criticise the evidence and share if its valid- peer review

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32

Problems with sharing findings of climate change

  • complex and difficult to model

  • see stories on the media that’re simplified or having bias- scientists must work hard to communicate ideas to general public

  • uncertainties

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33

Carbon footprint

  • Gives us an idea pf how much something contributes to climate change

  • Amount of CO2 and other greenhouse gases emitted over the full life cycleof a product

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34

Reducing CO2 emissions- energy

  • lot of energy used to heat our homes- often comes from burning fossil fuels

  • Insulate our homes or turn down heating

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35

Reducing CO2 emissions- cars

  • great deal of CO2 released from driving our cars

  • Reduce by using public transport- less CO2 per passenger

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36

Reducing CO2 emissions- electricity

  • produced by burning fossil fuels

  • reduce by switching to renewable forms of energy

  • reduce how much electricity u use at home e.g. energy saving bulbs or turn off plugs when not being used

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37

Problems with reducing CO2 emissions

  • most of solutions are expensive and people are reluctant to pay

  • Some are inconvenient

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38

Reducing methane emissions

  • biggest source are agriculture

    • grazing cattle release methane when they pass wind, one way is to reduce intake of meat

  • another source is landfills- can reduce by trapping methane n burning it to produce electricity

    • methane is much more powerful than CO2

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39

Problems with reducing methane emissions

  • people enjoy eating meat and are unlikely to change diet

  • trapping and burning methane costs money

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40

Pollutants from fuels

  • CO2

  • water vapour

  • carbon monoxide

  • sulfur dioxide

  • oxides of nitrogen

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41

When do fuels release energy?

  • when they’re combusted e.g. coal & hydrocarbons

    • coal used to generate electricity in power stations

    • hydrocarbon used to power vehicles

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42

What do most fuels include??

  • including coal and hydrocarbons

  • Contain carbon and hydrocarbons

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43

What happens when we burn fuels?

  • Carbon and hydrogen are oxidised

  • Complete combustion occurs when we’ve made CO2

  • Requires a lot of oxygen

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44

Where do we find the hydrocarbon methane?

In natural gas and used to heat homes

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45

What happens if oxygen is limited when combustion occurs?

  • produces carbon monoxide instead dioxide

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46

Carbon monoxide characteristics

  • toxic gas with no colour or smell

  • people have detectors in their homes

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47

What do SOME fuels contain??

  • contain element sulfur

  • e.g, coal

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48

What happens when coal is burned?- sulfur

Sulfur atoms are oxidised that produces gas sulfur dioxide- sulfur + oxygen —> sulfur dioxide

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49

Where are oxides of nitrogen produced?

  • produced in engines- high temps cause

  • N2 + O2 —> NOx

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50

What can sulfur dioxide and oxides of nitrogen cause??

  • cause breathing problems

  • form acid rain

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51

Acid rain

Damage trees, corrode buildings made from limestone

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52

Particles of carbon (soot) are called?

Particulates

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53

What can particulates and unburned hydrocarbons cause?

  • Can damage human health- increase risk of heart/lung disease

  • Reduce amount of energy from sun reaching surface- earth—> global dimming (affect rainfall patterns)

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