Electrolysis End of unit

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39 Terms

1
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At which electrode does oxidation happen during electrolysis?

The anode

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What is oxidation?

The loss of an electron

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What is reduction?

Gain of electrons

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Every metal besides .. and ., react with oxygen

Silver and gold

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How do you isolate elements below carbon in the reactivity series?

React them with carbon

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What are the rules of collection at the cathode?

If the metal is higher than hydrogen in the reactivity series, then hydrogen is made

If the metal is lower than hydrogen in the reactivity series, it costs the electrode.

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What are the rules of collection at the anode?

If halide ions are present, halogen gas is produced.

If halide ions aren’t present, oxygen is produced.

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What is an ore?

Contains a metal compound

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What is graphite made of?

Carbon and oxygen

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Why are graphite anodes replaced every month?

Carbon and Oxygen will slowly make Co2 as oxygen ions slowly hit the carbon. They break down and decompose.

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What is bouxile?

Aluminium oxide

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How is the charge carried in a solid circuit?

Delocalised electrons

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How is the charge carried in an electrolyte/solution? (the liquid at the bottom)

Ions

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How do halogens move around?

In pairs

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How is a gas collected at the anode?

Bubbles

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How do electrons move in electrolysis?

Carry the charge from one side to another

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What is another name from Sodium chloride solution?

Brine

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Why must things be molten or dissolved?

If not, ions cannot travel or move around to carry the charge between cathodes

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In a pure metal..

layers can slide over each other

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What does it mean if a solution is acidic?

There’s a high concentration of hydrogen ions

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What happens if a solution is alkali?

There’s a low concentration of hydrogen ions

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When the pH unit decreases by 1..

the hydrogen ion concentration in a solution increases by 10

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The more acidic the solution..

the higher the concentration of hydrogen

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Example of weak and strong acid

Weak = Vinegar

Strong = Hydrochloric

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What does cryolite do?

Reduces melting point of aluminium oxide so less energy is required

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Oxygen is produced at the positive electrode unless the solution contains..

Halide ions

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To conduct electricity in a solid,,

It must have delocalised electrons in the structure to carry the charge

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To conduct electricity in a liquid..

Ions must be available to move and carry the charge through the fluid

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What is a limiting reactant?

The one that runs our first

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Why do we add excess?

To ensure it’s all reacted

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Why are metal atoms always oxidised?

Metal atoms always lose electrons

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What is a redox reaction?

Oxidation and reduction happen at the same time

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What happens in electrolysis?

Compound decomposes or breaks down

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What happens at the cathode?

Positive ions gain electrons at the negative cathode

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What happens at the anode?

Negative ions lose electrons at the negative anode

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What happens in a molten compound?

Positive ions go to the cathode, negative ions go to the anode

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What happens in aqueous solutions?

Water contains hydrogen and hydroxide molecules, Positive ion goes to cathode unless more reactive than hydrogen, oxygen atom goes to anode unless halide ion is present

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