structure and bonding: radial wavefunctions

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7 Terms

1
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n=1, l=0 1s

  • wavelength isn’t 0 at nucleus

  • exponential decay

2
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n=2, l=1 2p

  • wavelength is 0 at nucleus

  • gradient isn’t 0 at nucleus

3
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ns

n-1 radial nodes

4
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np

n-2 radial nodes

5
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n=3, l=2 3d

  • wavelength 0 at nucleus

  • gradient 0 at nucleus

  • rate of change not 0

6
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radial distribution function

the probability of finding an electron at all points at that radius

7
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quantum numbers

  • n - orbital size (principal)

  • l - orbital shape (angular momentum)

  • Ml - orbital orientation (magnetic)