physical chemistry

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enthalpy change definition

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the overall change in energy in a reaction

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exothermic definition

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a process that releases heat to its surroundings, resulting in a decrease in enthalpy

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27 Terms

1

enthalpy change definition

the overall change in energy in a reaction

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2

exothermic definition

a process that releases heat to its surroundings, resulting in a decrease in enthalpy

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3

endothermic definition

a process that absorbs heat from its surroundings, resulting in an increase in enthalpy

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4

what process is it when bonds are broken in the reactants

endothermic

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5

what process is it when bonds are made in the products

exothermic

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6

calorimetry definition

process of measuring how much energy is absorbed or released in a chemical reaction

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7

specific heat capacity definition

how much energy it takes to raise the temperature of a unit mass of a substance by one degree celsius

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8

two examples of exothermic reactions

> combustion of fuels

> respiration

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9

two examples of endothermic reactions

> photosynthesis

> melting ice

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10

calculating rate of reaction

rate of reaction = amount of reactant used in amount of product formed / time taken

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11

factors affecting rate of reaction

> temperature

> catalyst

> concentration

> pressure

> surface area

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12

describe how you would compare the effectiveness of different catalysts on the rate of a reaction

  1. add the same mass of each catalyst to the reactants

  2. time how long it takes for a certain amount of product to be formed, or how long it takes for the reactant to get used up

  3. the catalyst that caused the product to be produced the fastest / reactant used up the fasted is the best catalyst

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13

describe what you can do at the end of a reaction to prove that the solid added acted as a catalyst and not as a reaction

  1. find the mass of the solid before the reaction starts

  2. allow the reaction to finish

  3. filter the products using a funnel and filter paper

  4. dry the remaining solid

  5. find the mass of the dry solid

  6. if the solid had acted as a catalyst the mass should be the same as it was in the beginning of the reaction

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14

how does temperature affect the rate of reactions

as temperature increases, particles have more kinetic energy, causing more successful collisions per unit time, increasing the rate of reaction

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15

how does catalysts affect the rate of reactions

it speeds up the rate of reaction by providing an alternative pathway, with a lower activation energy

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16

how does concentration affect the rate of reactions

as the concentration increases, there are more particles so more successful collisions per unit time so it increases rate of reaction

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17

how does surface area affect the rate of reactions

the reactant is more exposed when it has more surface area so there are more successful collisions per unit time so it increases the rate of reaction

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18

catalyst definition

a substance that speeds up a reaction without being used up

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19

reversible reaction

products of the reaction can react to produce the original reactants

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20

dynamic equilibrium definition

the forward and backward reaction is occurring at the same time are rate

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21

features of a reaction that is in dynamic equilibrium

> the forward and backward reaction occurs simultaneously

> the rate of the forward reaction is equal to the rate of the backward reaction

> the concentration of the reactants remain the same and the concentration of the products remain the same

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22

what happens to the equilibrium if the temperature is increased

the equilibrium shifts to the endothermic side

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23

what happens to the equilibrium if the temperature is decreased

the equilibrium shifts to the exothermic side

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24

what happens to the equilibrium if the pressure is increased

the equilibrium shifts to the side with the least amount of moles / particles

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25

what happens to the equilibrium if the pressure is decreased

the equilibrium shifts to the side with the least amount of moles / particles

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26

what happens to the equilibrium if the concentration is increased

the equilibrium shifts to the other side of the reaction that isnt affected

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27

what happens to the equilibrium if the concentration is decreased

the equilibrium shifts to the side where the concentration was decreased

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