Chapter 20: Carboxylic Acids

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4 Terms

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Formation of carboxylic acids

primary alcohols H2Cr2O4

Permanganate oxidation KMnO4

ozonolysis from terminal alkyne 1) O3 2) H2O

alkane side chains K2Cr2O7 and H2SO4

Grignard then 1) CO2 2) H3O+

hydrolysis of nitrile

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Fischer Esterification

creating an ester from a carboxylic acid and primary alcohol

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synthesis of acid chlorides

carboxylic acid and thionyl chloride (SOCl2)

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reduction of carboxylic acids

BH3*THF- converts to alcohol

DIBAL-H- converts to aldehyde

LiAl(OtBu)3H- converts to aldehyde