Ochem-Chapter 8

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9 Terms

1
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What reagents are used to make a Markovnikov alcohol product? Name the mechanism

1.Hg(OAC)2 2. NaBH4 ; Oxymercuration

2
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What reagents are used to make an anti-Markovnikov alcohol? Name the mechanism

1.BH3,THF 2.NAOH,H2O2; Hydroboration

3
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What reagents are used to turn an alkene into alkane? Name the mechanism

1.H2 2.Pd/C; Hydrogeneration

4
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What reagents are used to convert an alkene directly into an epoxide? Name the mechanism

mCPBA; Epoxidation

5
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What reagents are used to convert alkene into epoxide with halohydrin intermediate? Name the mechanism

Alkene —> Halohydrin: X2/H2O, Halohydrin —> Epoxide: KOH; Epoxidation

6
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What reagents are used to get trans-dial alcohol? Name the mechanism 

Alkene —> Epoxide: mCPBA / Epoxide —> Trans-dial alcohol: H30+; Hydroxylation

7
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What reagents are used to get cis-dial alcohol? Name the mechanism 

1.OsO4 2.NaHSO3 + H2O

8
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What reagents are used to get one or both of the following products Aldehyde/Ketone? Name the mechanism 

1.O3 2.Zn,H3O+

9
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What reagents are used to get one or both of the following products Carboxylic acid/Carbon Dioxide? Name the mechanism 

1.KMNO4 2.H3O+