mechanisms by which haloalkanes react with nucleophiles

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20 Terms

1
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poor nucleophile + methyl

no reaction

2
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poor nucleophile + primary (unhindered)

no reaction

3
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poor nucleophile + primary (hindered)

no reaction

4
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poor nucleophile + secondary

slow SN1, E1

5
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tertiary + poor nucleophile

Sn1, E1

6
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weakly basic, good nucleophile + methyl

SN2

7
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weakly basic, good nucleophile + primary (unhindered)

SN2

8
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weakly basic, good nucleophile + primary (branched)

SN2

9
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weakly basic, good nucleophile + secondary

SN2

10
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weakly basic, good nucleophile + tertiary

Sn1, E1

11
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strongly basic, unhindered nucelophile + methyl

SN2

12
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strongly basic, unhindered nucleophile + primary (unhindered)

Sn2

13
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strongly basic, unhindered nucleophile + primary (branched)

E2

14
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strongly basic, unhindered nucleophile + secondary

E2

15
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strongly basic, unhindered nucleophile + tertiary

E2

16
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strongly basic, hindered nucleophile + methyl

SN2

17
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strongly basic, hindered nucleophile + primary (unhindered)

E2

18
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strongly basic, hindered nucleophile + primary (hindered)

E2

19
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strongly basic, hindered nucleophile + secondary

E2

20
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strongly basic, hindered nucleophile + tertiary

E2