Cycloalkanes (Organic 3)

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22 Terms

1
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What are alkanes?

Saturated hydrocarbons with the general molecular formula CnH2n+2.

2
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What is the general molecular formula for alkanes?

CnH2n+2.

3
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How are hydrocarbons bonded?

By carbon-carbon and carbon-hydrogen single bonds.

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What is an alkyl group?

An alkane with one hydrogen atom removed.

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What is the I.U.P.A.C. naming convention for cycloalkanes?

Add the prefix cyclo- to the name of the alkane with the same number of carbons.

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What occurs during halogenation?

A halogen atom is substituted for one of the hydrogen atoms in an alkane.

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What are cis-trans isomers?

Stereoisomers of cycloalkanes that differ in the arrangement of substituents in space.

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What is stereoisomerism?

Molecules with the same structural formulas and bonding patterns but different arrangements of atoms in space.

9
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What is the significance of staggered conformation in alkanes?

It minimizes electron repulsion and is the most stable arrangement.

10
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What is the main product of the combustion of alkanes?

Carbon dioxide and water, along with heat energy.

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What is the difference between a cis configuration and a trans configuration in cycloalkanes?

Cis has both substituents on the same side of the ring; trans has one substituent above and one below.

12
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What is the chair conformation?

The most energetically favorable conformation for a six-membered ring.

13
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What is released during the combustion of hydrocarbons?

Heat energy, carbon dioxide, and water.

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What is created during the halogenation of an alkane?

An alkyl halide and hydrogen halide.

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What makes hydrocarbons useful as fuels?

Their energy released during combustion.

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What types of hydrocarbons can undergo combustion?

Alkanes, cycloalkanes, and other hydrocarbons.

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What compound is formed when chloroethane and chloromethane are used as anesthetics?

They act rapidly but their effect is brief due to rapid evaporation.

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What hazardous compounds are formed in swimming pools from chlorine?

Chloroform and trihalomethanes (THMs).

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What causes the formation of cis-trans isomers in cycloalkanes?

The formation of cis-trans isomers is a consequence of the absence of free rotation around the carbon-carbon bonds in the ring structure.

20
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What are conformations/conformers?

Conformations, or conformers, are different spatial arrangements of the same molecule that result from rotation around single bonds.

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How are chloroethane and chloromethane used in medicine?

as local anesthetics applied topically that act rapidly but have a brief effect due to rapid evaporation.

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What is Halothane?

It’s a general anesthetic that is administered by inhalation.