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Freshwater Textbook Sections 1 and 2
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What atoms is a water molecule made of, and what charges do each of the atoms have?
2 hydrogen atoms and 1 oxygen atom. Hydrogen has a partial positive charge, oxygen has a partial negative charge.
Due to uneven electrical charge distribution between oxygen and hydrogen atoms…
Water is a polar molecule
What is the attraction between hydrogen of one molecule and oxygen of another?
This attraction is called a hydrogen bond.
Cohesion
Cohesion is the attraction between molecules of the same substance.
Adhesion
Adhesion is the attraction between molecules of different substances.
What causes surface tension?
Cohesion helps water stay connected, causing surface tension.
What is capillary action?
Adhesion draws water, pulling additional water molecules, allowing water to move against gravity.
Solvent
A substance capable of dissolving other substances.
Why is water an effective solvent?
Because of its polarity
How does water dissolve ionic compounds?
Water molecules attract and separate ions of an ionic compound, which makes it dissolve.
What does it mean to be hydrophilic, and what type of substances are usually hydrophilic?
Polar substances are usually hydrophilic, meaning that they quickly and willingly interact with water.
What does it mean to be hydrophobic, and what type of substances are hydrophobic?
Non polar substances are generally hydrophobic, meaning that they do not interact with water, such as oil.
Why is chemically pure natural water very rare?
When water moves, dissolved substances travel with it.
Why is water’s solid form less dense than its liquid form?
As water freezes, hydrogen bonds arrange the molecules into a structure that holds them farther apart.
What does density depend on?
The amount of mass in a given volume
Specific heat
The amount of energy required to change the temperature of a substance
Why does water have a relatively high specific heat?
Hydrogen bonds absorb energy as they break and release energy as they form, so added thermal energy is partially used to disrupt hydrogen bonds.
Does water tend to cool and heat slower or faster than other substances?
Slower, because of its high specific heat.
Reservoir
A location where water is stored within Earth’s system: the largest reservoir is an ocean, others include glaciers, groundwater, lakes, rivers, soil, the atmosphere, and even living organisms.
Evaporation
Liquid water from Earth’s surface to the atmosphere as water vapor
Transpiration
Water from soil to atmosphere through plants
Evapotranspiration
Combined movement of water to atmosphere through evaporation and transpiration
Advection
Water vapor moving horizontally through the atmosphere by moving air
Condensation
Water vapor turns into liquid droplets
Precipitation
Water from atmosphere returns to Earth’s surface
Sublimation
Solid water turns to water vapor, skipping over liquid
Deposition/Desublimation
Water vapor to solid water (ice)
Runoff
Precipitation reaches land, some water moves across surface
Infiltration
Precipitation reaches land, some water enters soil
Groundwater recharge
Water that moves downward enough to replenish groundwater
The water cycle
A network of reservoirs connected by processes that transfer water between them
Water molecules movement for solid ice
Molecules are held in an organized structure by hydrogen bonds, and molecules vibrate but are fixed in position.
Water molecules movement for liquid water
Molecules remain close but can move past each other; hydrogen bonds constantly form and break
Water molecule movement for water vapor
Molecules are farther apart and move freely
Are clouds made of water vapor entirely?
No! The visible portion of clouds is mostly billions of water droplets or ice crystals.
Adiabatic cooling
When rising air expands causing the air to cool
Dewpoint
Temperature at which water vapor begins to condense
How do condensation nuclei help form water droplets?
Water molecules collect on these airborne particles, forming water droplets
Orographic lifting
Air forced upwards over mountains
Ways air can rise
Air can rise from uneven heating, orographic lifting, or be lifted when air masses meet.
Cloud formation sequence
Air rises → air expands → air cools → water vapor condenses → cloud droplets form
Latent heat
Energy absorbed or released during a phase change
What phase changes absorb energy?
Evaporation, melting, and sublimation
What phase changes release energy?
Condensation, freezing, and deposition
Watershed
A watershed (drainage basin) is an area of land from which water drains towards a common outlet
Watershed divides generally follow…
Ridges and hills
Pathways for water entering a watershed
Precipitation → runoff → surface-water storage → evaporation or downstream flow
Precipitation → infiltration → soil-water storage → evaporation or plant uptake and transpiration
Precipitation → infiltration → percolation → groundwater recharge and storage → groundwater discharge
Water budget
Compares the amount of water entering and leaving a system
How to calculate water budget
Inputs - Outputs = Change in storage
Surplus
Inputs > outputs
Deficit
Outputs > inputs
Soil water budget
The water available in soil
Potential evapotranspiration (Ep)
The amount of water that could be transferred to the atmosphere through evapotranspiration if enough water were available
Actual evapotranspiration (Ea)
The amount of evapotranspiration that actually occurs
Recharge
Precipitation > water demand, so soil-water storage refills
Surplus
Soil-water storage reaches capacity, additional water available
Soil water usage
Depletion of stored soil water, precipitation does not provide enough water to meet plant and atmospheric demand
Deficit
Soil-water storage fully depleted, Ea < Ep
Soil water budget patterns in climates like Massachusetts
Recharge → surplus → usage → deficits → recharge
Permeable surface
A surface that allows water to infiltrate into the ground (usually soils and vegetated areas)
Impermeable surface
A surface that allows little or no infiltration (rooftops, paved surfaces)
What does more impermeable surfaces mean
More surface runoff, water reaches storm drains quickly
Stream discharge
Volume of flow per unit of time
Hydrographs
Hydrographs are graphs showing how stream discharge changes over time
When does stream discharge increase?
After a storm
Stream discharge in permeable lands
Stream discharge rises slower and reaches a lower peaks
Stream discharge in impermeable lands
Stream discharge rises quickly to a higher peak