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energy
the ability to do work or produce heat
potential energy
so tired energy based on position if an object
kinetic energy
energy an object has due to its motion
thermal energy
sum of all the potential and kinetic energies an object has
temperature
measure of the average kinetic energy of all particles of a given substance (relates to speed of particles)
intermolecular forces (IMFs)
forces of attraction that cause particles of matter to “stick together” (attraction between particles)
exothermic
process where energy is released ( will have (-) sign when the change of energy is calculated)
endothermic
process where energy is absorbed (will have a (+) sign when the change of energy is calculated)
ethalpy (H)
official term for total “heat content” of a system (total thermal energy contained in a sample)
calorie (cal)
alternative unit of energy used in chemistry due to its relationship to heating and cooling water
energy needed to heat 1 gram of water by 1 degree C
Calorie (Cal)
dietary nutrition
Specific heat capacity ( c ) - reference value
heating or cooling one gram of a substance by one degree celsius
J/g degree celsius or cal/g degree celsius
molar heat of phase change - reference value (delta H degrees)
1 mole of a substance undergoing a phase change
KJ/mol or Kcal/mol
heat source
hotter thing - molecules traveling at greater speeds
Heat sink
molecules traveling at slower speeds
thermal equilibrium
heat continues to flow between the two objects until they have the same temperature (exchange energy until they are traveling at the same average speed)
phase boundaries
division between separate phases
phase equilibrium
rate of change into one state is the same as the rate of change into other state (ex. rate of vaporization is equal to the rate of condensation) occurs on all points directly on the boundary
triple point (T)
temperature and pressure at which solid, liquid, and gas phases exist simultaneously (end of solid-liquid phase boundary)
critical point ( c )
temperature above which a substance will always be a gas regardless of the pressure
super critical fluid
state of any substance at a temperature and pressure above its critical point where distinct liquid and gas phases don’t exist (in between liquid and gas)
vapor pressure
pressure of the vapor resulting from evaporation of a liquid
“volatility” - how easily a substance enters the vapor phase
boiling point
temperature at which vapor pressure of the liquid is equal to the atmospheric pressure
normal boiling point
temperature at which a substance boils at standard pressure
normal melting point
temperature at which a substance melts at standard pressure
mixture
physical blend instead of a chemical bond
homogeneous mixture
uniformly distributed; mixture is the same throughout
heterogeneous mixture
no uniform throughout the mixture
solution
homogeneous mixture of very small particles
solute
substance that dissolves ; present in smaller amounts
solvent
the substance that does the dissolving; present in larger amounts
colloid
a type of homogenous mixture that the particles are dispersed and evenly distributed and do not settle out
suspension
a heterogeneous mixture that contains solid particles sufficiently large that they will settle if left out standing
soluble (general)
able to dissolve in a certain solvent
insoluble (general)
not able to dissolve in a certain solvent
miscible
when two liquids are mixed they will for a homogeneous structure
immiscible
when two liquids are mixed together and they are not capable of forming a homogeneous mixture (i.e. water and oil)
dissolving
when a solid becomes incorporated into a liquid
concentrated
having a relatively large amount of solute dissolved in the solvent
dilute
a relative low amount is solutes dissolved in the solvent
to make a solution thinner or less concentrated by adding water or another solvent to it
saturated
maximum amount is solute has been dissolved
unsaturated
concentration is lower than it could be, there is still more room to dissolve more solute
supersaturated
solution that contains more of the dissolved material that could be dissolved by the solvent under normal circumstances
solubility
the maximum amount is solute that can dissolve in a given temperature and pressure (amount is solute that will saturate the solvent)
colligative properti w
property of a solution that depends on the with or solute dissolved, not the identity of the solute (all solutes behave in the same manner)