Cation Synthons & Synthetic Equivalents

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5 Terms

1
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R+

  • R-I

  • R-Br

  • R-OSO2Me (R-OMs)

  • R-OTs

2
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<p>HO-C<sup>+</sup></p>

HO-C+

Ketone/aldehyde

<p>Ketone/aldehyde</p>
3
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<p>HO-C-C<sup>+</sup></p>

HO-C-C+

Epoxide

<p>Epoxide</p>
4
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<p>O=C<sup>+</sup>-R</p>

O=C+-R

Carboxylic acid derivatives

e.g. X=

  • Cl

  • OCOR

  • OR

  • NR2

  • CO2

<p>Carboxylic acid derivatives</p><p>e.g. X=</p><ul><li><p>Cl</p></li><li><p>OCOR</p></li><li><p>OR</p></li><li><p>NR<sub>2</sub></p></li><li><p>CO<sub>2</sub></p></li></ul><p></p>
5
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<p>R(O=)C-CH<sub>2</sub>-C<sup>+</sup></p>

R(O=)C-CH2-C+

α,β-unsaturated carbonyl

<p>α,β-unsaturated carbonyl</p>