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Ion Exchange
Removal of NH3 Exchange with Ca
Zeolite Water Softerning
Began on the 1st Decade of the 20th Century
Processed Greensand
Bentonitic Clay
Synthetic Gel type minerals
Synthetic Resin Exhangers
Type of Ion Exhcanges
Inorganic Zeolites
Composed Principally of Hydrated Alkali alumina-silicates
Polystyrene-Based Sulfonated-synthetic-resin type
Sulfonated-coal type
2 Most widely used Hydrogen Cation Exchangers
large Closed Cylindrical Tank
Automatic Zeolite Softener
Equipment used in Ion Exhange
Cation Organic Exchanger
Anion Organic Exchanger
Two Classes of Ion Exchange
Synthetic Organic Resin
Processed Natural Organic Materials
Ion Exchange Cation types
Highly Basic type
Weakly Basic Type
Ion Exchange Anion types
Lime-Soda Process
Method of Softening Hard water
Hot or Cold
Lime-Soda Process is carried out either __________
Carbonate
Magnesium
Sulfate
Micro-organism
Dissolved Organic Matter
Lime soda process removes
30 mg/L
minimum calcium hardness can be achieve
10 mg/L
minimum magnesium hardness can be achieve
Power Plants
Textile Industries
Breweries & Distilleries
Oil Refineries
Municipal Water Treatment
Industries that uses Lime soda processfor water softening includeL
Phosphate Conditioning
Process used in Internal Conditioning of Boiler water and Conditioning of cooling & Process water
9.5
calcium cannot be precipitated below a pH of ____
Scale Formation
avoided in high pressure boilers by adding sodium phosphate
Trisodium Phosphate
Sodium Hydrogen Phosphate
Sodium Dihydrogen Phosphate
Types of Phosphates
Trisodium Phosphate
Alkaline in nature: used when alkalinity is low or highly acidic water
Sodium Hydrogen Phosphate
weakly Alkaline: Used when Alkalinity is sufficient or slightly acidic water
Sodium Dihydrogen Phosphate
Acidic: Used when Alkalinity is High
Storage Systems
Chemical Feed Equipment
Monitoring Equipment
Control Systems
Equipment Used in Phosphate Conditioning
Corrosion Control
pH adjustmnets
2 types of Phosphate Conditioning
Corrosion Control
Phosphate provides a Protective Layer on the metal surface of the pipe
pH Adjustments
Phosphate conditioning helps maintain the pH levels of water within operational range
Easy operation
Used for neutral water
Applied to high pressure boilers
highly acidic or alkaline water can be treated
water of nearly zero hardness can be obtained
Advantages of Phosphate Conditioning
Silica Removal
Prevents premature wear or damage to industrial equipment
Si- Silica
28% of Earth’s crust is composed of____
Granular
Colloidal
Ionic
Types of Silica
Granular
Exist in water as relatively large particles
Colloidal
consist of finer particles comparative to granular
Ionic
consist of finer particles comparative to colloidal
Limes softening
Ultrafiltration
Reverse Osmosis
Methods of Removing Silica
Lime Softening
Process where calcium hydroxide is added to water to remove hardness via precipitation
Ultra Filtration
Uses a flexible filter with tiny pores
Reverse Osmosis
Uses a semi-permeable membrane to separate out ions and particles from a liquid stream
Reduce energy consumption & maintenance expense
Guarantee high-quality water
Increase equipment Lifespan
Benefits of Silica Removal
Deaerator
a device that is used for the removal of Dissolved Gases
Spray-Type
also know as “Spray-Scrubber” composed of a single horizontal or vertical vessel
Tray-type
also known as “ Spray-Tray” usually comprises two vessels
Spraying
Stream Flow
Stream Scrubbing
Venting
Process in Deaeration
Henry’s law
Inverse Solubility of Water
Principles involved in Deaeration of water
Chemical Scavengers
used to react with residual oxygen to ensure complete removal of oxygen
Sodium Sulfite
Hydrazine
Carbohydrazide
Examples of Chemical Scavengers
Demineralization
Process of removing Dissolved minerals from water using Ion Exchange
Desalination
Process of removing Salts and Impurities from sea water to produce fresh portable water
Cation Exchange
Anion Exchange
Process involve in Demineralization
Cation Exchange Unit
Anion Exchange Unit
Mixed-Bed Exchange
Regeneration System
Equipment used in Demineralization
Reverse Osmosis
Multi-Stage Flash Distillation
Electrodialysis
Chemical & Physical Reactions Involved in Desalitation
High-Pressure Pumps
RO membranes
Energy recovery devices
Equipment used in Desalination (Reverse Osmosis)
Boilers/heaters
Flash Chambers
Condensers
Equipment used in Desalination (Multi-Stage Flash Distillation)
Electrodialysis stack
Electrodes(anodes &cathods)
PSU
Equipment used in Desalination (ElectroDialysis)
Water Purification
Removal of Organic matter and Micro-Organism from untreated water to produce safe & clean drinking water
Coagulation-Flocculation
Sedimentation
Filtration
Disinfection
Water purification process
Filtration
Sedimentation
Physical Methods of purification
Filtration
Physical Methods of filtration Type: Uses physical Barriers
Sedimentation
Physical Methods of filtration Type: Gravity-Based Separation
Chemical Coagulation
Flocculation
Disinfection
Chemical methods of Purification
Chemical Coagulation
Chemical methods of Purification Type: neutralizes the charge & forms a gelatinous mass
Flocculation
Chemical methods of Purification Type: Helps particles bind together into larger clumps
Disinfection
Chemical methods of Purification Type: Eliminates Pathogens
Coagulation: Chemical mixing tanks, Dosing pumps
Sedimentation: Clarifier tanks , Settler Units
Filtration: Membrane Filters, Sand Filters, Carbon Filters
Disinfection: Chlorine Dosing, UV units, Ozone genarators
Equipment used in Purification
Coagulation reaction
Purification Chemical reaction types: Removes suspended particles using coagulants to form large clumps
Disinfection Reaction
Purification Chemical reaction types: Kill harmful Micro-organism
Alum
Common coagulant in water treatment
Metal Salt Coagulation
Coagulation reactions: uses metal coagulants like aluminum sulfate
Chlorination
Coagulation reactions: Water disinfection method that uses chlorine
Hypochlorous acid
Enters microbes and disrupts their functions
Ozonation
Coagulation reactions: uses ozone to purify water